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Structural complexity of(Na0.5Bi0.5)TiO3-BaTiO3as revealed by Raman spectroscopy

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Wylie-van Eerd, Ben, Damjanovic, Dragan, Klein, Naama, Setter, Nava, Trodahl, Joe·2010·Physical Review B

Abstract

The structural phase diagram of the Pb-free ferroelectric ${({\text{Na}}_{1/2}{\text{Bi}}_{1/2})}_{1\ensuremath{-}x}{\text{Ba}}_{x}{\text{TiO}}_{3}$, $x<0.1$, has been explored by Raman spectroscopy at temperatures from 10 to 470 K. The data provide clear evidence for a proposed temperature-independent morphotropic phase boundary at $x\ensuremath{\approx}0.055$. However, there is no evidence for a structural phase transition across $T\ensuremath{\approx}370\text{ }\text{K}$ for $x>0.055$, where bulk-property anomalies appear to signal a transition to a nonpolar or antiferroelectric phase. The results identify that the phase above 370 K shows short-range ionic displacements that are identical to those in the long-range-ordered phase below 370 K. These conclusions provide a natural interpretation of the weak piezoelectric response in this system and have important implications for the search for Pb-free piezoelectrics.

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Metadata

Authors
Wylie-van Eerd, B., Damjanovic, D., Klein, N., Setter, N., & Trodahl, J.
Venue
Physical Review B
Published
2010-09-17
Volume
82
Issue
10
ISSN
  • 1098-0121 (ISSN-L)
  • 1550-235X
OpenAlex
W1510855962
Cited by
303
References
23
FWCI
9.27
Type
journal article
Language
en
Open access
green

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Wylie-van Eerd, B., Damjanovic, D., Klein, N., Setter, N., & Trodahl, J. (2010). Structural complexity of(Na0.5Bi0.5)TiO3-BaTiO3as revealed by Raman spectroscopy. Physical Review B. https://doi.org/10.1103/physrevb.82.104112

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