The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
First-principles study of the oxygen evolution reaction of lithium peroxide in the lithium-air battery
Open accessAbstract
The lithium-air chemistry is an interesting candidate for the next-generation batteries with high specific energy. However, this new battery technology is facing substantial challenges, such as a high overpotential upon charging, poor reversibility, and low power density. Using first-principles calculations, we study the oxygen evolution reaction (OER) on the low-index surfaces of lithium peroxide. The elementary reaction steps and the energy profile of the OER are identified on the low-index surfaces of lithium peroxide. We find that the OER processes are kinetically limited by the high energy barrier for the evolution of oxygen molecules and that the rate of the OER processes is highly dependent on the surface orientation.
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Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Cited by
A Reversible and Higher-Rate Li-O 2 Battery
Peng, Z., Freunberger, S. A., Chen, Y., & Bruce, P. G. (2012) · Science · doi:10.1126/science.1223985 · Cited by 1,915
The Carbon Electrode in Nonaqueous Li–O2 Cells
Ottakam Thotiyl, M. M., Freunberger, S. A., Peng, Z., & Bruce, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja310258x · Cited by 1,249
Charging a Li–O2 battery using a redox mediator
Chen, Y., Freunberger, S. A., Peng, Z., Fontaine, O., & Bruce, P. G. (2013) · Nature Chemistry · doi:10.1038/nchem.1646 · Cited by 937
Current density dependence of peroxide formation in the Li–O2 battery and its effect on charge
Adams, B. D., Radtke, C., Black, R., Trudeau, M. L., Zaghib, K., & Nazar, L. F. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40697k · Cited by 678
Hautier, G., Ong, S. P., Jain, A., Moore, C. J., & Ceder, G. (2012) · Physical Review B · doi:10.1103/physrevb.85.155208 · Cited by 506
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Metadata
- Authors
- Mo, Y., Ong, S. P., & Ceder, G.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2011-11-21
- Volume
- 84
- Issue
- 20
- ISSN
- 1098-0121 (ISSN-L)
- 1550-235X
- OpenAlex
- W1480903124
- Cited by
- 220
- References
- 1
- FWCI
- 11.59
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Mo, Y., Ong, S. P., & Ceder, G. (2011). First-principles study of the oxygen evolution reaction of lithium peroxide in the lithium-air battery. Physical Review B. https://doi.org/10.1103/physrevb.84.205446
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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