The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Current density dependence of peroxide formation in the Li–O2 battery and its effect on charge
Abstract
We report a significant difference in the growth mechanism of Li2O2 in Li–O2 batteries for toroidal and thin-film morphologies which is dependent on the current rate that governs the electrochemical pathway. Evidence from diffraction, electrochemical, FESEM and STEM measurements shows that slower current densities favor aggregation of lithium peroxide nanocrystallites nucleated via solution dismutase on the surface of the electrode; whereas fast rates deposit quasi-amorphous thin films. The latter provide a lower overpotential on charge due to their nature and close contact with the conductive electrode surface, albeit at the expense of lower discharge capacity.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
A Reversible and Higher-Rate Li-O 2 Battery
Peng, Z., Freunberger, S. A., Chen, Y., & Bruce, P. G. (2012) · Science · doi:10.1126/science.1223985 · Cited by 1,915
An improved high-performance lithium–air battery
Jung, H.-G., Hassoun, J., Park, J.-B., Sun, Y.-K., & Scrosati, B. (2012) · Nature Chemistry · doi:10.1038/nchem.1376 · Cited by 1,089
Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li–O2 Batteries
McCloskey, B. D., Speidel, A., Scheffler, R., Miller, D. C., Viswanathan, V., Hummelshøj, J. S., Nørskov, J. K., & Luntz, A. C. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz300243r · Cited by 1,073
Laoire, C. O., Mukerjee, S., Abraham, K. M., Plichta, E. J., & Hendrickson, M. A. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp102019y · Cited by 974
Lithium–oxygen batteries: bridging mechanistic understanding and battery performance
Lu, Y.-C., Gallant, B. M., Kwabi, D. G., Harding, J. R., Mitchell, R. R., Whittingham, M. S., & Shao-Horn, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee23966g · Cited by 927
Screening for Superoxide Reactivity in Li-O2 Batteries: Effect on Li2O2/LiOH Crystallization
Black, R., Oh, S. H., Lee, J.-H., Yim, T., Adams, B., & Nazar, L. F. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2111543 · Cited by 695
Self-citationElucidating the Mechanism of Oxygen Reduction for Lithium-Air Battery Applications
Laoire, C. O., Mukerjee, S., Abraham, K. M., Plichta, E. J., & Hendrickson, M. A. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp908090s · Cited by 663
Oxygen Reactions in a Non‐Aqueous Li+ Electrolyte
Peng, Z., Freunberger, S. A., Hardwick, L. J., Chen, Y., Giordani, V., Bardé, F., Novák, P., Graham, D., Tarascon, J., & Bruce, P. G. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100879 · Cited by 595
Viswanathan, V., Thygesen, K. S., Hummelshøj, J. S., Nørskov, J. K., Girishkumar, G., McCloskey, B. D., & Luntz, A. C. (2011) · The Journal of Chemical Physics · doi:10.1063/1.3663385 · Cited by 583
Cited by
Artificial Protection Film on Lithium Metal Anode toward Long‐Cycle‐Life Lithium–Oxygen Batteries
Liu, Q., Xu, J., Yuan, S., Chang, Z., Xu, D., Yin, Y., Li, L., Zhong, H., Jiang, Y., Yan, J., et al. (2015) · Advanced Materials · doi:10.1002/adma.201501490 · Cited by 482
From lithium to sodium: Cell chemistry of room temperature sodium–air and sodium–sulfur batteries
Adelhelm, P., Hartmann, P., Bender, C. L., Busche, M., Eufinger, C., & Janek, J. (2015) · Beilstein Journal of Nanotechnology · doi:10.3762/bjnano.6.105 · Cited by 478
Critical Challenges in Rechargeable Aprotic Li–O2 Batteries
Feng, N., He, P., & Zhou, H. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502303 · Cited by 423
Metadata
- Authors
- Adams, B. D., Radtke, C., Black, R., Trudeau, M. L., Zaghib, K., & Nazar, L. F.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 6
- Issue
- 6
- Pages
- 1772
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2159411932
- Cited by
- 678
- References
- 27
- FWCI
- 51.72
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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