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Effect of disorder on Raman scattering of single-layerMoS2

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Mignuzzi, Sandro, Pollard, Andrew J., Bonini, Nicola, Brennan, Barry, Gilmore, Ian S., Pimenta, Marcos A., Richards, David, Roy, Debdulal·2015·Physical Review B

Abstract

We determine the effect of defects induced by ion bombardment on the Raman spectrum of single-layer molybdenum disulfide. The evolution of both the linewidths and frequency shifts of the first-order Raman bands with the density of defects is explained with a phonon confinement model, using density functional theory to calculate the phonon dispersion curves. We identify several defect-induced Raman scattering peaks arising from zone-edge phonon modes. Among these, the most prominent is the $\mathrm{LA}(M)$ peak at $\ensuremath{\sim}227\phantom{\rule{0.16em}{0ex}}\mathrm{c}{\mathrm{m}}^{\ensuremath{-}1}$ and its intensity, relative to the one of first-order Raman bands, is found to be proportional to the density of defects. These results provide a practical route to quantify defects in single-layer $\mathrm{Mo}{\mathrm{S}}_{2}$ using Raman spectroscopy and highlight an analogy between the $\mathrm{LA}(M)$ peak in $\mathrm{Mo}{\mathrm{S}}_{2}$ and the $D$ peak in graphene.

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Metadata

Authors
Mignuzzi, S., Pollard, A. J., Bonini, N., Brennan, B., Gilmore, I. S., Pimenta, M. A., Richards, D., & Roy, D.
Venue
Physical Review B
Published
2015-05-11
Volume
91
Issue
19
ISSN
  • 1098-0121 (ISSN-L)
  • 1550-235X
OpenAlex
W2284566726
Cited by
784
References
4
FWCI
15.85
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Effect of disorder on Raman scattering of single-layerMoS2. https://app.cochat.ai/papers/10.1103/physrevb.91.195411
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Mignuzzi, S., Pollard, A. J., Bonini, N., Brennan, B., Gilmore, I. S., Pimenta, M. A., Richards, D., & Roy, D. (2015). Effect of disorder on Raman scattering of single-layerMoS2. Physical Review B. https://doi.org/10.1103/physrevb.91.195411

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