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Enhancement of the Infrared Absorption from Molecular Monolayers with Thin Metal Overlayers
Abstract
The infrared absorption from molecular monolayers is enhanced a factor of 20 by thin metal overlayers or underlayers with use of the attenuated-total-reflection technique. The total enhancement, including contributions from the attenuated-total-reflection geometry, is almost ${10}^{4}$. This effect is consistent with an electric field enhancement due to collective electron resonances associated with the island nature of the thin metal films.
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Cites
Surface raman spectroelectrochemistry
Jeanmaire, D. L., & Van Duyne, R. P. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80224-6 · Cited by 4,738
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Morton, S. M., Silverstein, D. W., & Jensen, L. (2011) · Chemical Reviews · doi:10.1021/cr100265f · Cited by 474
All-Dielectric Surface-Enhanced Infrared Absorption-Based Gas Sensor Using Guided Resonance
Chang, Y., Hasan, D., Dong, B., Wei, J., Ma, Y., Zhou, G., Ang, K. W., & Lee, C. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b16623 · Cited by 115
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Hwang, I., Yu, J., Lee, J., Choi, J.-H., Choi, D.-G., Jeon, S., Lee, J., & Jung, J.-Y. (2018) · ACS Photonics · doi:10.1021/acsphotonics.8b00702 · Cited by 63
Slit-Enhanced Chiral- and Broadband Infrared Ultra-Sensing
Knipper, R., Kopecký, V., Huebner, U., Popp, J., & Mayerhöfer, T. G. (2018) · ACS Photonics · doi:10.1021/acsphotonics.8b00476 · Cited by 39
Use of nano gold obtained by laser ablation for SEIRA analyses of colorants
Prati, S., Quaranta, M., Sciutto, G., Bonacini, I., Litti, L., Meneghetti, M., & Mazzeo, R. (2014) · Heritage Science · doi:10.1186/s40494-014-0028-8 · Cited by 14
Metadata
- Authors
- Hartstein, A., Kirtley, J. R., & Tsang, J. C.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1980-07-21
- Volume
- 45
- Issue
- 3
- Pages
- 201-204
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W1977630559
- Cited by
- 681
- References
- 1
- FWCI
- 10.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hartstein, A., Kirtley, J. R., & Tsang, J. C. (1980). Enhancement of the Infrared Absorption from Molecular Monolayers with Thin Metal Overlayers. Physical Review Letters. https://doi.org/10.1103/physrevlett.45.201
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