Cited by 181Surface Chemistry and CatalysisElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

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Observation of Rotational Excitations ofH2Adsorbed on Ag Surfaces

Avouris, Ph., Schmeisser, D., Demuth, J. E.·1982·Physical Review Letters

Abstract

High-resolution electron-energy-loss studies of ${\mathrm{H}}_{2}$ on Ag at \ensuremath{\sim} 10 K reveal both rotational and rotational-vibrational excitations of molecularly adsorbed and condensed ${\mathrm{H}}_{2}$. The rotational losses for submonolayers of adsorbed ${\mathrm{H}}_{2}$ indicate unhindered rotational motion as well as a H-H internuclear separation which is within \ensuremath{\sim}2% of that of condensed ${\mathrm{H}}_{2}$. Adsorbed ${\mathrm{H}}_{2}$ is also converted from predominantly orthohydrogen to parahydrogen.

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Research works printed but not linked: 18

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Metadata

Authors
Avouris, P., Schmeisser, D., & Demuth, J. E.
Affiliations
IBM Research - Thomas J. Watson Research Center (US)
Venue
Physical Review Letters
Published
1982-01-18
Volume
48
Issue
3
Pages
199-202
ISSN
0031-9007 (ISSN-L)
OpenAlex
W2058296579
Cited by
181
References
0
Citations by year
2026: 1 · 2025: 2 · 2024: 1 · 2023: 2 · 2022: 1 · 2021: 3 · 2020: 3 · 2019: 2 · 2018: 2 · 2017: 1 · 2016: 5 · 2015: 4 · 2014: 4 · 2013: 8 · 2012: 3
FWCI
12.89
Type
journal article
Language
en
Open access
closed
Locations
Physical Review Letters (publishedVersion)
Topics
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Surface Chemistry and Catalysis
  • Physical Sciences › Materials Science › Surfaces, Coatings and Films › Electron and X-Ray Spectroscopy Techniques
  • Physical Sciences › Physics and Astronomy › Condensed Matter Physics › Surface and Thin Film Phenomena
Keywords
molecular hydrogen adsorption, silver surface, rotational excitation, electron energy loss spectroscopy, submonolayer adsorption, hydrogen condensation, low-temperature adsorption

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CoChat. (2026). Citation check: Observation of Rotational Excitations ofH2Adsorbed on Ag Surfaces. https://app.cochat.ai/papers/10.1103/physrevlett.48.199
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Avouris, P., Schmeisser, D., & Demuth, J. E. (1982). Observation of Rotational Excitations ofH2Adsorbed on Ag Surfaces. Physical Review Letters. https://doi.org/10.1103/physrevlett.48.199