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Transition-Metal Monoxides: Band or Mott Insulators
Abstract
We argue that the widely held view that MnO, FeO, CoO, and NiO are Mott insulators is incorrect. Intra-atomic potential energies do not dominate interatomic kinetic energies, to the extent commonly believed; both are 1-2 eV in magnitude. A measure of the importance of interatomic effects is our finding that both the crystal structure and the magnetic structure of these materials are crucial to their insulating behavior.
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Citations
Cited by
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
Dudarev, S. L., Botton, G. A., Savrasov, S. Y., Humphreys, C. J., & Sutton, A. P. (1998) · Physical Review B · doi:10.1103/physrevb.57.1505 · Cited by 15,173
Electronic structure ofCu2O and CuO
Ghijsen, J., Tjeng, L. H., van Elp, J., Eskes, H., Westerink, J., Sawatzky, G. A., & Czyzyk, M. T. (1988) · Physical Review B · doi:10.1103/physrevb.38.11322 · Cited by 1,644
Reproducible resistance switching in polycrystalline NiO films
Seo, S., Lee, M. J., Seo, D. H., Jeoung, E. J., Suh, D.-S., Joung, Y. S., Yoo, I. K., Hwang, I. R., Kim, S. H., Byun, I. S., et al. (2004) · Applied Physics Letters · doi:10.1063/1.1831560 · Cited by 933
Transition-metal oxides in the self-interaction–corrected density-functional formalism
Svane, A., & Gunnarsson, O. (1990) · Physical Review Letters · doi:10.1103/physrevlett.65.1148 · Cited by 649
Ab initio study of MnO and NiO
Towler, M. D., Allan, N. L., Harrison, N. M., Saunders, V. R., Mackrodt, W. C., & Aprà, E. (1994) · Physical Review B · doi:10.1103/physrevb.50.5041 · Cited by 481
Metadata
- Authors
- Terakura, K., Williams, A. R., Oguchi, T., & Kübler, J.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1984-05-14
- Volume
- 52
- Issue
- 20
- Pages
- 1830-1833
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W2067061948
- Cited by
- 275
- References
- 0
- FWCI
- 11.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Transition-Metal Monoxides: Band or Mott Insulators. https://app.cochat.ai/papers/10.1103/physrevlett.52.1830
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- Terakura, K., Williams, A. R., Oguchi, T., & Kübler, J. (1984). Transition-Metal Monoxides: Band or Mott Insulators. Physical Review Letters. https://doi.org/10.1103/physrevlett.52.1830
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
