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Polymers on Nanoperiodic, Heterogeneous Surfaces
Abstract
Herein we establish a relationship between controlled nanoscale surface interactions and subsequent macromolecular ordering. Striped surfaces of oxide and metal are generated over large areas, where the stripe width is comparable to the size of a polymer molecule. Homopolymers are found to anisotropically dewet such surfaces, while incompatible polymer mixtures phase separate at the substrate/polymer interface on a molecular level. An orientation of lamellar block copolymer microdomains normal to the surface is found, when substrate and polymer length scales are commensurate.
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Citations
Cited by
Dynamics and stability of thin liquid films
Craster, R. V., & Matar, O. K. (2009) · Reviews of Modern Physics · doi:10.1103/revmodphys.81.1131 · Cited by 1,441
Directing the self-assembly of block copolymers
Darling, S. B. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.05.004 · Cited by 1,019
Block copolymer based nanostructures: Materials, processes, and applications to electronics
Kim, H.-C., Park, S.-M., & Hinsberg, W. D. (2010) · Chemical Reviews · doi:10.1021/cr900159v · Cited by 1,017
Directed Assembly of Block Copolymer Blends into Nonregular Device-Oriented Structures
Stoykovich, M. P., Müller, M., Kim, S. O., Solak, H. H., Edwards, E. W., de Pablo, J. J., & Nealey, P. F. (2005) · Science · doi:10.1126/science.1111041 · Cited by 962
Patterning with block copolymer thin films
Segalman, R. A. (2005) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2004.12.003 · Cited by 954
Metadata
- Authors
- Rockford, L., Liu, Y., Mansky, P., Russell, T. P., Yoon, M., & Mochrie, S. G. J.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1999-03-22
- Volume
- 82
- Issue
- 12
- Pages
- 2602-2605
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W1996714618
- Cited by
- 446
- References
- 0
- FWCI
- 17.73
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rockford, L., Liu, Y., Mansky, P., Russell, T. P., Yoon, M., & Mochrie, S. G. J. (1999). Polymers on Nanoperiodic, Heterogeneous Surfaces. Physical Review Letters. https://doi.org/10.1103/physrevlett.82.2602
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
