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Polarization Rotation via a Monoclinic Phase in the Piezoelectric 92%PbZn1/3Nb2/3O3-8%PbTiO3
Open accessAbstract
The origin of ultrahigh piezoelectricity in the relaxor ferroelectric ${\mathrm{PbZn}}_{1/3}{\mathrm{Nb}}_{2/3}{\mathrm{O}}_{3}\ensuremath{-}{\mathrm{PbTiO}}_{3}$ was studied with an electric field applied along the [001] direction. The zero-field rhombohedral $R$ phase starts to follow the direct polarization path to tetragonal symmetry via an intermediate monoclinic $M$ phase, but then jumps irreversibly to an alternate path involving a different type of monoclinic distortion. Details of the structure and domain configuration of this novel phase are described. This result suggests that there is a nearby $R\ensuremath{-}M$ phase boundary as found in the $\mathrm{Pb}(\mathrm{Ti},\mathrm{Zr}){\mathrm{O}}_{3}$ system.
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Citations
Cited by
Large Piezoelectric Effect in Pb-Free Ceramics
Liu, W., & Ren, X. (2009) · Physical Review Letters · doi:10.1103/physrevlett.103.257602 · Cited by 2,764
Contributions to the piezoelectric effect in ferroelectric single crystals and ceramics
Damjanovic, D. (2005) · Journal of the American Ceramic Society · doi:10.1111/j.1551-2916.2005.00671.x · Cited by 708
Ultrahigh Piezoelectric Properties in Textured (K,Na)NbO3‐Based Lead‐Free Ceramics
Li, P., Zhai, J., Shen, B., Zhang, S., Li, X., Zhu, F., & Zhang, X. (2018) · Advanced Materials · doi:10.1002/adma.201705171 · Cited by 555
Structure and high-piezoelectricity in lead oxide solid solutions
Noheda, B. (2002) · Current Opinion in Solid State and Materials Science · doi:10.1016/s1359-0286(02)00015-3 · Cited by 448
Self-citationKim, H.-P., Kang, W.-S., Hong, C.-H., Lee, G.-J., Choi, G., Ryu, J., & Jo, W. (2020) · Advanced Ceramics for Energy Conversion and Storage · doi:10.1016/b978-0-08-102726-4.00005-3 · Cited by 9
Metadata
- Authors
- Noheda, B., Cox, D. E., Shirane, G., Park, S.-E., Cross, L. E., & Zhong, Z.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2001-04-23
- Volume
- 86
- Issue
- 17
- Pages
- 3891-3894
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2015375971
- Cited by
- 702
- References
- 0
- FWCI
- 33.69
- Type
- journal article
- Language
- en
- Open access
- green
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- Noheda, B., Cox, D. E., Shirane, G., Park, S.-E., Cross, L. E., & Zhong, Z. (2001). Polarization Rotation via a Monoclinic Phase in the Piezoelectric 92%PbZn1/3Nb2/3O3-8%PbTiO3. Physical Review Letters. https://doi.org/10.1103/physrevlett.86.3891
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