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Ultrafast Time-Resolved Soft X-Ray Photoelectron Spectroscopy of DissociatingBr2
Abstract
The dissociation of excited state Br2 is probed with the novel technique of ultrafast soft x-ray photoelectron spectroscopy. Excited Br2 molecules are prepared in the dissociative (1)Pi(u) state with 80 fs, 400 nm pulses, and a series of photoelectron spectra are obtained during dissociation with pulses of soft x-ray light (47 nm, 26.4 eV, 250 fs). The formation of Br atoms is readily detected and the data support an extremely fast dissociation time for Br2 on the order of 40 fs. Amplitudes of the pump-probe features reveal that the ionization cross section of atomic Br at 47 nm is approximately 40 times larger than that of Br2.
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Citations
Cited by
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Winterfeldt, C., Spielmann, C., & Gerber, G. (2008) · Reviews of Modern Physics · doi:10.1103/revmodphys.80.117 · Cited by 384
Kling, M. F., & Vrakking, M. J. J. (2008) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.59.032607.093532 · Cited by 334
Loh, Z.-H., & Leone, S. R. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz301910n · Cited by 66
Self-citationTime-resolved high-harmonic spectroscopy of the photodissociation of CH3I and CF3I
Tehlar, A., & Wörner, H. J. (2013) · Molecular Physics · doi:10.1080/00268976.2013.782439 · Cited by 23
Metadata
- Authors
- Nugent-Glandorf, L., Scheer, M., Samuels, D. A., Mulhisen, A. M., Grant, E. R., Yang, X., Bierbaum, V. M., & Leone, S. R.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2001-10-22
- Volume
- 87
- Issue
- 19
- Pages
- 193002-193002
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2036519744
- Cited by
- 175
- References
- 0
- FWCI
- 7.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Nugent-Glandorf, L., Scheer, M., Samuels, D. A., Mulhisen, A. M., Grant, E. R., Yang, X., Bierbaum, V. M., & Leone, S. R. (2001). Ultrafast Time-Resolved Soft X-Ray Photoelectron Spectroscopy of DissociatingBr2. Physical Review Letters. https://doi.org/10.1103/physrevlett.87.193002
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