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Ultrafast Time-Resolved Soft X-Ray Photoelectron Spectroscopy of DissociatingBr2

Nugent-Glandorf, Lora, Scheer, Michael, Samuels, David A., Mulhisen, Anneliese M., Grant, Edward R., Yang, Xueming, Bierbaum, Veronica M., Leone, Stephen R.·2001·Physical Review Letters

Abstract

The dissociation of excited state Br2 is probed with the novel technique of ultrafast soft x-ray photoelectron spectroscopy. Excited Br2 molecules are prepared in the dissociative (1)Pi(u) state with 80 fs, 400 nm pulses, and a series of photoelectron spectra are obtained during dissociation with pulses of soft x-ray light (47 nm, 26.4 eV, 250 fs). The formation of Br atoms is readily detected and the data support an extremely fast dissociation time for Br2 on the order of 40 fs. Amplitudes of the pump-probe features reveal that the ionization cross section of atomic Br at 47 nm is approximately 40 times larger than that of Br2.

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Metadata

Authors
Nugent-Glandorf, L., Scheer, M., Samuels, D. A., Mulhisen, A. M., Grant, E. R., Yang, X., Bierbaum, V. M., & Leone, S. R.
Venue
Physical Review Letters
Published
2001-10-22
Volume
87
Issue
19
Pages
193002-193002
ISSN
  • 0031-9007 (ISSN-L)
  • 1079-7114
OpenAlex
W2036519744
Cited by
175
References
0
FWCI
7.31
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Ultrafast Time-Resolved Soft X-Ray Photoelectron Spectroscopy of DissociatingBr2. https://app.cochat.ai/papers/10.1103/physrevlett.87.193002
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Nugent-Glandorf, L., Scheer, M., Samuels, D. A., Mulhisen, A. M., Grant, E. R., Yang, X., Bierbaum, V. M., & Leone, S. R. (2001). Ultrafast Time-Resolved Soft X-Ray Photoelectron Spectroscopy of DissociatingBr2. Physical Review Letters. https://doi.org/10.1103/physrevlett.87.193002

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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