Capturing Ultrafast Quantum Dynamics with Femtosecond and Attosecond X-ray Core-Level Absorption Spectroscopy
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Recent technical advances in ultrafast laser sources enable the generation of femtosecond and attosecond soft X-ray pulses in tabletop laser setups as well as accelerator-based synchrotron and free-electron laser sources. These new light sources can be harnessed via pump-probe spectroscopy to elucidate ultrafast quantum dynamics in atoms, molecules, and condensed matter with unprecedented time resolution and chemical sensitivity. Employing such ultrashort pulses in transient X-ray absorption spectroscopy combines the unique advantages of core-level absorption probing of chemical environments and oxidation states with the ability to obtain ultimately freeze-frame snapshots of electronic and nuclear dynamics. In this Perspective, we provide an overview of the progress in applying the recently developed technique of femtosecond to attosecond time-resolved soft X-ray transient absorption spectroscopy to the study of ultrafast phenomena, including some of our own efforts to elucidate the interaction of intense laser pulses with atoms and molecules in the strong-field, nonperturbative limit. Possible avenues for future work are outlined.
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Core-level transient-absorption spectroscopy is a method that is element specific, and sensitive to oxidation states and spin states, and is applicable to a wide range of chemical elements and species.
“Core-level transient-absorption spectroscopy [215], a method that is element specific, and sensitive to oxidation states and spin states, is applicable to a wide range of chemical elements and species.”
From Roadmap of ultrafast x-ray atomic and molecular physics (2018) · cites this paper as [215]
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- Authors
- Loh, Z.-H., & Leone, S. R.
- Affiliations
- Nanyang Technological University (SG)
- Lawrence Berkeley National Laboratory (US)
- Corresponding author
- Leone, Stephen R.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-01-04
- Volume
- 4
- Issue
- 2
- Pages
- 292-302
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2029911536
- Cited by
- 66
- References
- 111
- Citations by year
- 2026: 2 · 2025: 3 · 2023: 5 · 2022: 1 · 2021: 3 · 2019: 2 · 2018: 9 · 2017: 5 · 2016: 14 · 2015: 6 · 2014: 10 · 2013: 6
- FWCI
- 3.64
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Locations
- The Journal of Physical Chemistry Letters (publishedVersion)
- PubMed (publishedVersion)
- DR-NTU (Nanyang Technological University) (submittedVersion)
- Funders
- National Science Foundation (0310717, 1049946)
- U.S. Department of Defense
- U.S. Department of Energy (-AC02-05CH11231, DE AC02 05CH11231, DE-AC02-)
- W. M. Keck Foundation
- Office of Science (DEAC02–05CH11231, DE-AC02)
- Division of Chemistry
- Basic Energy Sciences (DE-AC02, DE-AC02-05CH11231., AC02–05CH11231)
- Laboratory Directed Research and Development
- Lawrence Berkeley National Laboratory (DE-AC02-05CH11231)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
- Physical Sciences › Physics and Astronomy › Radiation › X-ray Spectroscopy and Fluorescence Analysis
- Physical Sciences › Physics and Astronomy › Radiation › Advanced X-ray Imaging Techniques
- Keywords
- core-level absorption, femtosecond X-ray pulses, attosecond X-ray pulses, pump-probe spectroscopy, transient absorption spectroscopy, intense laser-matter interaction, oxidation state, chemical environment, free-electron laser, synchrotron radiation
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