The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Direct Visualization of Random Crystallization and Melting in Arrays of Nanometer-Size Polymer Crystals
Abstract
Using tapping mode atomic force microscopy, we visualized in direct space and time resolved the changes in viscoelastic properties during crystallization and melting of polyethyleneoxide in 12 nm spheres of a block copolymer mesophase. All spheres crystallized individually and independently, randomly distributed sphere by sphere. Melting of the confined crystals also proceeded in a stochastic manner. Not all spheres melted at the same temperature, indicating different degrees of order of the individual nanometer-size polymer crystals. The independence of the spheres opens the possibility to manipulate material properties of surfaces at the nanometer scale.
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Citations
Cites
Structure Development in Semicrystalline Diblock Copolymers Crystallizing from the Ordered Melt
Ryan, A. J., Hamley, I. W., Bras, W., & Bates, F. S. (1995) · Macromolecules · doi:10.1021/ma00115a016 · Cited by 233
Cited by
Rodrı́guez, T. R., & Garcı́a, R. (2004) · Applied Physics Letters · doi:10.1063/1.1642273 · Cited by 295
Nucleation and Crystallization in Diblock and Triblock Copolymers
Müller, A. J., Balsamo, V., & Arnal, M. L. (2005) · Advances in Polymer Science · doi:10.1007/12_001 · Cited by 294
Homogeneous nucleation and fractionated crystallization in block copolymers
Müller, A. J., Balsamo, V., Arnal, M. L., Jakob, T., Schmalz, H., & Abetz, V. (2002) · Macromolecules · doi:10.1021/ma012026w · Cited by 226
Duran, H., Steinhart, M., Butt, H.-J., & Floudas, G. (2011) · Nano Letters · doi:10.1021/nl200153c · Cited by 197
Massa, M. V., & Dalnoki-Veress, K. (2004) · Physical Review Letters · doi:10.1103/physrevlett.92.255509 · Cited by 192
Metadata
- Authors
- Reiter, G., Castelein, G., Sommer, J.-U., Röttele, A., & Thurn-Albrecht, T.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2001-11-07
- Volume
- 87
- Issue
- 22
- Pages
- 226101-226101
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2076351537
- Cited by
- 198
- References
- 1
- FWCI
- 11.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- Reiter, G., Castelein, G., Sommer, J.-U., Röttele, A., & Thurn-Albrecht, T. (2001). Direct Visualization of Random Crystallization and Melting in Arrays of Nanometer-Size Polymer Crystals. Physical Review Letters. https://doi.org/10.1103/physrevlett.87.226101
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
