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Hydrodynamics within the Electric Double Layer on Slipping Surfaces
Open accessAbstract
We show, using extensive molecular dynamics simulations, that the dynamics of the electric double layer (EDL) is very much dependent on the wettability of the charged surface on which the EDL develops. For a wetting surface, the dynamics, characterized by the so-called zeta potential, is mainly controlled by the electric properties of the surface, and our work provides a clear interpretation for the traditionally introduced immobile Stern layer. In contrast, the immobile layer disappears for nonwetting surfaces, and the zeta potential deduced from electrokinetic effects is considerably amplified by the existence of a slippage at the solid substrate.
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Cited by
Reddy, L. H., Arias, J. L., Nicolas, J., & Couvreur, P. (2012) · Chemical Reviews · doi:10.1021/cr300068p · Cited by 2,010
Bazant, M. Z., Kilic, M. S., Storey, B. D., & Ajdari, A. (2009) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2009.10.001 · Cited by 916
Interfacial Water at Hydrophobic and Hydrophilic Surfaces: Slip, Viscosity, and Diffusion
Sendner, C., Horinek, D., Bocquet, L., & Netz, R. R. (2009) · Langmuir · doi:10.1021/la901314b · Cited by 567
Self-citationWater Slippage versus Contact Angle: A Quasiuniversal Relationship
Huang, D. M., Sendner, C., Horinek, D., Netz, R. R., & Bocquet, L. (2008) · Physical Review Letters · doi:10.1103/physrevlett.101.226101 · Cited by 527
Self-citationDielectric measurement of individual microtubules using the electroorientation method
Minoura, I., & Muto, E. (2006) · Biophysical Journal · doi:10.1529/biophysj.105.071324 · Cited by 156
Metadata
- Authors
- Joly, L., Ybert, C., Trizac, E., & Bocquet, L.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2004-12
- Volume
- 93
- Issue
- 25
- Pages
- 257805-257805
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2130214491
- Cited by
- 327
- References
- 0
- FWCI
- 4.67
- Type
- journal article
- Language
- en
- Open access
- green
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- Joly, L., Ybert, C., Trizac, E., & Bocquet, L. (2004). Hydrodynamics within the Electric Double Layer on Slipping Surfaces. Physical Review Letters. https://doi.org/10.1103/physrevlett.93.257805
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