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The crystal structure of arsenic at 4.2, 78 and 299°K
Abstract
The lattice constants and the atomic position parameter, z, of a high purity, low strain, single-crystal of arsenic have been determined. Low extinction reflections of filtered Mo Kα and Ag Kα radiation were used for the determination of z. The Bond precision technique with Mo Kα radiation was used for the determination of the unit-cell dimensions a and c. Average values for a and c in Å, and for z are: 4.2°K z = 0.22764 a = 3.7597 c = 10.4412; 78°K z = 0.22754 a = 3.7595 c = 10.4573; 299±3°K z = 0.22707 a = 3.7598 c = 10.5475. The estimated standard deviation of z is ±0.00004 at 4.2°K, ±0.00002 at 78°K and ±0.00005 at 299°K. The precision of a is estimated to be ±0–0001 Å and that for c to be ±0.0002 Å. The results for As are compared with those reported earlier for Sb and Bi.
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Cited by
Milman, V., Winkler, B., White, J. A., Pickard, C. J., Payne, M. C., Akhmatskaya, E. V., & Nobes, R. H. (2000) · International Journal of Quantum Chemistry · doi:10.1002/(sici)1097-461x(2000)77:5<895::aid-qua10>3.0.co;2-c · Cited by 1,755
Arsenene: Two-dimensional buckled and puckered honeycomb arsenic systems
Kamal, C., & Ezawa, M. (2015) · Physical Review B · doi:10.1103/physrevb.91.085423 · Cited by 874
A foundation model for atomistic materials chemistry
Batatia, I., Benner, P., Chiang, Y., Elena, A. M., Kovács, D. P., Riebesell, J., Advincula, X. R., Asta, M., Avaylon, M., Baldwin, W. J., et al. (2024) · arXiv · doi:10.48550/arxiv.2401.00096 · Cited by 604
Thermal conductance of interfaces between highly dissimilar materials
Lyeo, H.-K., & Cahill, D. G. (2006) · Physical Review B · doi:10.1103/physrevb.73.144301 · Cited by 576
A foundation model for atomistic materials chemistry
Batatia, I., Benner, P., Chiang, Y., Elena, A. M., Kovács, D. P., Riebesell, J., Advincula, X. R., Asta, M., Avaylon, M., Baldwin, W. J., et al. (2025) · The Journal of Chemical Physics · doi:10.1063/5.0297006 · Cited by 566
Metadata
- Authors
- Schiferl, D., & Barrett, C. S.
- Venue
- Journal of Applied Crystallography
- Published
- 1969-05-01
- Volume
- 2
- Issue
- 1
- Pages
- 30-36
- ISSN
- 0021-8898 (ISSN-L)
- OpenAlex
- W2056323984
- Cited by
- 275
- References
- 0
- FWCI
- 2.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schiferl, D., & Barrett, C. S. (1969). The crystal structure of arsenic at 4.2, 78 and 299°K. Journal of Applied Crystallography. https://doi.org/10.1107/s0021889869006443
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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