The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Dependence of the Fictive Temperature of Glass on Cooling Rate
Abstract
An equation derived by Ritland relating the cooling rate and fictive temperature for glasses without memory is extended to those with memory, i.e. those which exhibit a spectrum of relaxation times. Provided that the spectrum of relaxation times is temperature‐independent, the limiting fictive temperature, T′ f , obtained when a glass is cooled through the transition region, is shown to be related to the cooling rate, q , by d In | q |/ d (1/ T'f )=‐Δ h ★/ R where R is the ideal gas constant and Δ h ★ the activation enthalpy for the relaxation times controlling the structural relaxation. Values of T′ f vs q obtained from enthalpy measurements by differential scanning calorimetry are presented for B 2 O 3 , 0.4Ca(NO 3 ) 2 —0.6KNO 3 , and borosilicate crown glasses; Δ h ★ is equal, within experimental error, to the activation enthalpy for shear viscosity. Values of T′ f from volume and enthalpy measurements obtained at the same cooling rate for the borosilicate crown glass are equal.
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Citations
Cites
A Model of Structural Relaxation in Glass
NARAYANASWAMY, O. S. (1971) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1971.tb12186.x · Cited by 1,534
RELATION BETWEEN INELASTIC DEFORMABILITY AND THERMAL EXPANSION OF GLASS IN ITS ANNEALING RANGE*
Tool, A. Q. (1946) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1946.tb11592.x · Cited by 1,481
Modern Aspects of the Vitreous State
Mackenzie, J. D., & Rice, S. A. (1961) · Physics Today · doi:10.1063/1.3057162 · Cited by 1,218
Dependence of the glass transition temperature on heating and cooling rate
Moynihan, C. T., Easteal, A. J., Wilder, J., & Tucker, J. (1974) · The Journal of Physical Chemistry · doi:10.1021/j100619a008 · Cited by 1,010
Self-citationAnalysis of Structural Relaxation in Glass Using Rate Heating Data
DEBOLT, M. A., EASTEAL, A. J., MACEDO, P. B., & MOYNIHAN, C. T. (1976) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1976.tb09377.x · Cited by 544
Self-citationDensity Phenomena in the Transformation Range of a Borosilicate Crown Glass
RITLAND, H. N. (1954) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1954.tb14053.x · Cited by 228
Limitations of the Fictive Temperature Concept
Ritland, H. N. (1956) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1956.tb15613.x · Cited by 201
Inadequacies of Viscosity Theories for B2O3
Macedo, P. B., & Napolitano, A. (1968) · The Journal of Chemical Physics · doi:10.1063/1.1670321 · Cited by 136
Thermodynamic properties from differential scanning calorimetry by calorimetric methods
Flynn, J. H. (1974) · Thermochimica Acta · doi:10.1016/0040-6031(74)85073-2 · Cited by 103
Effects of a distribution of volume relaxation times in the annealing of bsc glass
Macedo, P. B., & Napolitano, A. (1967) · Journal of Research of the National Bureau of Standards Section A Physics and Chemistry · doi:10.6028/jres.071a.031 · Cited by 90
Cited by
Enthalpy relaxation and recovery in amorphous materials
Hodge, I. M. (1994) · Journal of Non-Crystalline Solids · doi:10.1016/0022-3093(94)90321-2 · Cited by 1,206
Hutchinson, J. M. (1995) · Progress in Polymer Science · doi:10.1016/0079-6700(94)00001-i · Cited by 1,045
STRUCTURAL RELAXATION IN VITREOUS MATERIALS*
Moynihan, C. T., Macedo, P. B., Montrose, C. J., Montrose, C. J., Gupta, P. K., DeBolt, M. A., Dill, J. F., Dom, B. E., Drake, P. W., Easteal, A. J., et al. (1976) · Annals of the New York Academy of Sciences · doi:10.1111/j.1749-6632.1976.tb39688.x · Cited by 848
Self-citationBaird, J. A., Van Eerdenbrugh, B., & Taylor, L. S. (2010) · Journal of Pharmaceutical Sciences · doi:10.1002/jps.22197 · Cited by 697
Understanding Glass through Differential Scanning Calorimetry
Zheng, Q., Zhang, Y., Montazerian, M., Gulbiten, O., Mauro, J. C., Zanotto, E. D., & Yue, Y. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00510 · Cited by 465
Metadata
- Authors
- MOYNIHAN, C. T., EASTEAL, A. J., De BOLT, M. A., & TUCKER, J.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 1976-01
- Volume
- 59
- Issue
- 1-2
- Pages
- 12-16
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W2128997946
- Cited by
- 1,241
- References
- 12
- FWCI
- 10.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- MOYNIHAN, C. T., EASTEAL, A. J., De BOLT, M. A., & TUCKER, J. (1976). Dependence of the Fictive Temperature of Glass on Cooling Rate. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.1976.tb09376.x
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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