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Chemically Bonded Phosphate Ceramics: I, A Dissolution Model of Formation
Abstract
This is the first of three papers in which the kinetics of formation of chemically bonded phosphate ceramics is discussed. A literature survey indicates that the formation of such ceramics is a three‐step process. First, oxides dissolve in a phosphoric acid or an acid phosphate solution and metal ions are released into the solution. The aquoions formed from these cations then react with phosphate anions and form a gel of metal hydrophosphates. In the last step, the saturated gel crystallizes into a ceramic. In this paper, we have proposed that the dissolution is the controlling step and developed a general dissolution model of the kinetics of formation of these ceramics. As an example, the model is used to discuss the kinetics of formation of magnesium phosphate ceramics in detail. In the second and third papers, the model has been used to develop processes to form ceramics of alumina and iron oxides.
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Citations
Cited by
Magnesia-based cements: a journey of 150 years, and cements for the future?
Walling, S. A., & Provis, J. L. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00463 · Cited by 984
Research progresses on magnesium phosphate cement: A review
Haque, M. A., & Chen, B. (2019) · Construction and Building Materials · doi:10.1016/j.conbuildmat.2019.03.304 · Cited by 348
Novel magnesium phosphate cements with high early strength and antibacterial properties
Mestres, G., & Ginebra, M.-P. (2011) · Acta Biomaterialia · doi:10.1016/j.actbio.2010.12.008 · Cited by 306
Metadata
- Authors
- Wagh, A. S., & Jeong, S. Y.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 2003-11
- Volume
- 86
- Issue
- 11
- Pages
- 1838-1844
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W2118128672
- Cited by
- 335
- References
- 0
- FWCI
- 5.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wagh, A. S., & Jeong, S. Y. (2003). Chemically Bonded Phosphate Ceramics: I, A Dissolution Model of Formation. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.2003.tb03569.x
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
