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Modifications to the Freundlich equation to describe anion sorption over a large range and to describe competition between pairs of ions
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Summary We measured sorption of selenite and phosphate, both separately and in competition, in a Chilean Andisol. We also used previously published data for competitive sorption of arsenate and phosphate by a clay subsoil. We wrote computer programs that allowed us to compare the fits of differing versions of equations to describe individual sorption and competitive sorption. For the selenite–phosphate data, the index term of the Freundlich equation decreased as concentration increased. This was described using the Sibbesen modification of the Freundlich equation. This modification was then included in competition equations. For both the selenite–phosphate and the arsenate–phosphate data, competition was not ‘symmetrical’, that is, the competition terms were not reciprocals of each other. We think this occurred because competition between ions is not only competition for adsorption sites but also involves electrical effects that follow penetration of the surface.
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“Competition for surface sites appears evident when the competing anions have a similar affinity for the surface of the sorbent (e.g., arsenate and phosphate), whereas the influence of electric potential is more important when competition occurs between ligands with a great different affinity for the sorbent (e.g., arsenate and sulfate) [6, 51].”
From Chemical Processes Affecting the Mobility of Heavy Metals and Metalloids in Soil Environments (2016) · cites this paper as [51]
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Metadata
- Authors
- Barrow, N. J., Cartes, P., & Mora, M. L.
- Affiliations
- Universidad de La Frontera (CL)
- Corresponding author
- Barrow, N. J.
- Venue
- European Journal of Soil Science
- Publisher
- Wiley
- Published
- 2005-01-13
- Volume
- 56
- Issue
- 5
- Pages
- 601-606
- ISSN
- 1351-0754 (ISSN-L)
- 1365-2389
- OpenAlex
- W2054824475
- Cited by
- 58
- References
- 11
- Citations by year
- 2025: 3 · 2024: 2 · 2023: 7 · 2022: 2 · 2021: 3 · 2020: 4 · 2019: 1 · 2017: 1 · 2015: 4 · 2014: 1 · 2013: 3 · 2012: 8
- FWCI
- 9.66
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- European Journal of Soil Science (publishedVersion)
- LA Referencia (Red Federada de Repositorios Institucionales de Publicaciones Científicas) (publishedVersion, other-oa)
- UWA Profiles and Research Repository (University of Western Australia) (submittedVersion)
- Americanae (AECID Library) (submittedVersion, other-oa)
- Omeka S (Universidad de La Frontera) (submittedVersion, cc-by-nc-nd)
- Topics
- Physical Sciences › Environmental Science › Waste Management and Disposal › Phosphorus and nutrient management
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Clay minerals and soil interactions
- Keywords
- anion sorption, competitive adsorption, Freundlich isotherm, selenite, phosphate, arsenate, volcanic ash soil, clay subsoil, adsorption site competition
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