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A laboratory survey of the thermal desorption of astrophysically relevant molecules
Open accessAbstract
The thermal desorption characteristics of 16 astrophysically relevant species from laboratory analogues of the icy mantles on interstellar dust grains have been surveyed in an extensive set of preliminary temperature programmed desorption experiments. The species can be separated into three categories based on behaviour. Water‐like species have a single relevant desorption coincident with water. CO‐like species show the volcano desorption and co‐desorption of trapped molecules, monolayer desorption from the surface of water ice, and multilayer desorption if initially present in sufficient abundance in an outer layer separated from the water ice. Intermediate species show the two desorptions of trapped molecules, and may show a small monolayer desorption for molecules small enough to have a limited ability to diffuse through the structure of porous amorphous water ice. Methods by which the results obtained under laboratory conditions can be adapted for astrophysical situations are discussed.
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Citations
Cited by
Complex Organic Interstellar Molecules
Herbst, E., & van Dishoeck, E. F. (2009) · Annual Review of Astronomy and Astrophysics · doi:10.1146/annurev-astro-082708-101654 · Cited by 1,759
THE SPITZER ICE LEGACY: ICE EVOLUTION FROM CORES TO PROTOSTARS
Öberg, K. I., Boogert, A. C. A., Pontoppidan, K. M., van den Broek, S., van Dishoeck, E. F., Bottinelli, S., Blake, G. A., & Evans, N. J. (2011) · The Astrophysical Journal · doi:10.1088/0004-637x/740/2/109 · Cited by 567
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Öberg, K. I. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00694 · Cited by 474
The ancient heritage of water ice in the solar system
Cleeves, L. I., Bergin, E. A., Alexander, C. M. O., Du, F., Graninger, D., Öberg, K. I., & Harries, T. J. (2014) · Science · doi:10.1126/science.1258055 · Cited by 305
The comet-like composition of a protoplanetary disk as revealed by complex cyanides
Öberg, K. I., Guzmán, V. V., Furuya, K., Qi, C., Aikawa, Y., Andrews, S. M., Loomis, R., & Wilner, D. J. (2015) · Nature · doi:10.1038/nature14276 · Cited by 260
Metadata
- Authors
- Collings, M. P., Anderson, M. A., Chen, R., Dever, J. W., Viti, S., Williams, D. A., & McCoustra, M. R. S.
- Venue
- Monthly Notices of the Royal Astronomical Society
- Publisher
- Oxford University Press (OUP)
- Published
- 2004-11-11
- Volume
- 354
- Issue
- 4
- Pages
- 1133-1140
- ISSN
- 0035-8711 (ISSN-L)
- 1365-2966
- OpenAlex
- W2096249383
- Cited by
- 609
- References
- 0
- FWCI
- 6.70
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Collings, M. P., Anderson, M. A., Chen, R., Dever, J. W., Viti, S., Williams, D. A., & McCoustra, M. R. S. (2004). A laboratory survey of the thermal desorption of astrophysically relevant molecules. Monthly Notices of the Royal Astronomical Society. https://doi.org/10.1111/j.1365-2966.2004.08272.x
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