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Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

Jochum, Klaus Peter, Weis, Ulrike, Stoll, Brigitte, Kuzmin, Dmitry, Yang, Qichao, Raczek, Ingrid, Jacob, Dorrit E., Stracke, Andreas, Birbaum, Karin, Frick, Daniel A., Günther, Detlef, Enzweiler, Jacinta·2011·Geostandards and Geoanalytical Research

Abstract

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.

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Crossref · 10.1111/j.1751-908x.2011.00120.x

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Metadata

Authors
Jochum, K. P., Weis, U., Stoll, B., Kuzmin, D., Yang, Q., Raczek, I., Jacob, D. E., Stracke, A., Birbaum, K., Frick, D. A., Günther, D., & Enzweiler, J.
Venue
Geostandards and Geoanalytical Research
Publisher
Wiley
Published
2011-06-06
Volume
35
Issue
4
Pages
397-429
ISSN
  • 0150-5505 (ISSN-L)
  • 1639-4488
  • 1751-908X
OpenAlex
W2085064498
Cited by
2,112
References
12
FWCI
40.10
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines. https://app.cochat.ai/papers/10.1111/j.1751-908x.2011.00120.x
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Jochum, K. P., Weis, U., Stoll, B., Kuzmin, D., Yang, Q., Raczek, I., Jacob, D. E., Stracke, A., Birbaum, K., Frick, D. A., Günther, D., & Enzweiler, J. (2011). Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines. Geostandards and Geoanalytical Research. https://doi.org/10.1111/j.1751-908x.2011.00120.x

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