The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Dynamics of Water Molecules in Aqueous Solvation Shells
Abstract
We report on the direct measurement of the dynamics of water molecules in the solvation shell of an ion in aqueous solution. The hydrogen-bond dynamics of water molecules solvating a Cl − , Br − , or I − anion is slow compared with neat liquid water, indicating that the aqueous solvation shells of these ions are rigid. This rigidity can play an important role in the overall dynamics of chemical reactions in aqueous solution. The experiments were performed with femtosecond midinfrared nonlinear spectroscopy, because this technique allows the spectral response of the water molecules in the solvation shell to be distinguished clearly from that of the other water molecules in the solution.
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Cites
Hydrogen bonding in solids correlation of spectroscopic and crystallographic data
Novak, A. (2007) · Springer eBooks · doi:10.1007/bfb0116438 · Cited by 1,417
Femtosecond solvation dynamics of water
Jimenez, R., Fleming, G. R., Kumar, P. V., & Maroncelli, M. (1994) · Nature · doi:10.1038/369471a0 · Cited by 1,272
Computer simulations of NaCl association in polarizable water
Smith, D. E., & Dang, L. X. (1994) · The Journal of Chemical Physics · doi:10.1063/1.466363 · Cited by 1,167
Effects of Ion Atmosphere on Hydrogen-Bond Dynamics in Aqueous Electrolyte Solutions
Chandra, A. (2000) · Physical Review Letters · doi:10.1103/physrevlett.85.768 · Cited by 580
Femtosecond Mid-IR Pump-Probe Spectroscopy of Liquid Water: Evidence for a Two-Component Structure
Woutersen, S., Emmerichs, U., & Bakker, H. J. (1997) · Science · doi:10.1126/science.278.5338.658 · Cited by 579
Self-citationResonant intermolecular transfer of vibrational energy in liquid water
Woutersen, S., & Bakker, H. J. (1999) · Nature · doi:10.1038/990058 · Cited by 553
Self-citationMikenda, W. (1986) · Journal of Molecular Structure · doi:10.1016/0022-2860(86)87054-5 · Cited by 354
Vibrational Spectroscopy of the Cl-(H2O)n Anionic Clusters, n = 1−5
Choi, J.-H., Kuwata, K. T., Cao, Y.-B., & Okumura, M. (1998) · The Journal of Physical Chemistry A · doi:10.1021/jp9729425 · Cited by 217
Hydrogen Bond in Liquid Water as a Brownian Oscillator
Woutersen, S., & Bakker, H. J. (1999) · Physical Review Letters · doi:10.1103/physrevlett.83.2077 · Cited by 195
Self-citationMicroscopic hydration of the fluoride anion
Cabarcos, O. M., Weinheimer, C. J., Lisy, J. M., & Xantheas, S. S. (1999) · The Journal of Chemical Physics · doi:10.1063/1.478075 · Cited by 192
Cited by
Interactions between macromolecules and ions: the Hofmeister series
Zhang, Y., & Cremer, P. S. (2006) · Current Opinion in Chemical Biology · doi:10.1016/j.cbpa.2006.09.020 · Cited by 2,100
How Ions Affect the Structure of Water
Hribar, B., Southall, N. T., Vlachy, V., & Dill, K. A. (2002) · Journal of the American Chemical Society · doi:10.1021/ja026014h · Cited by 860
Levine, R. D. (2005) · Cambridge University Press eBooks · doi:10.1017/cbo9780511614125 · Cited by 709
Marx, D., Chandra, A., & Tuckerman, M. E. (2010) · Chemical Reviews · doi:10.1021/cr900233f · Cited by 522
Understanding specific ion effects and the Hofmeister series
Gregory, K. P., Elliott, G. R., Robertson, H., Kumar, A., Wanless, E. J., Webber, G. B., Craig, V. S. J., Andersson, G. G., & Page, A. J. (2022) · Physical Chemistry Chemical Physics · doi:10.1039/d2cp00847e · Cited by 462
Metadata
- Authors
- Kropman, M. F., & Bakker, H. J.
- Venue
- Science
- Published
- 2001-03-16
- Volume
- 291
- Issue
- 5511
- Pages
- 2118-2120
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2064596479
- Cited by
- 465
- References
- 15
- FWCI
- 12.26
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
