The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Magneto-Opto-Electronic Bistability in a Phenalenyl-Based Neutral Radical
Abstract
A new organic molecular conductor, based on a spiro-biphenalenyl neutral radical, simultaneously exhibits bistability in three physical channels: electrical, optical, and magnetic. In the paramagnetic state, the unpaired electrons are located in the exterior phenalenyl units of the dimer, whereas in the diamagnetic state the electrons migrate to the interior phenalenyl units and spin pair as a π-dimer. Against all expectations, the conductivity increases by two orders of magnitude in the diamagnetic state, and the band gap decreases. This type of multifunctional material has the potential to be used as the basis for new types of electronic devices, where multiple physical channels are used for writing, reading, and transferring information.
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Self-citationSitzmann, H., Bock, H. R., Boese, R., Dezember, T., Havlas, Z., Kaim, W., Moscherosch, M., & Zanathy, L. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00078a043 · Cited by 72
Cited by
Multifunctional Shape‐Memory Polymers
Behl, M., Razzaq, M. Y., & Lendlein, A. (2010) · Advanced Materials · doi:10.1002/adma.200904447 · Cited by 971
Synthetic organic spin chemistry for structurally well-defined open-shell graphene fragments
Morita, Y., Suzuki, S., Sato, K., & Takui, T. (2011) · Nature Chemistry · doi:10.1038/nchem.985 · Cited by 656
Room-Temperature Ferromagnetism of Graphene
Wang, Y., Huang, Y., Song, Y., Zhang, X., Ma, Y., Liang, J., & Chen, Y. (2009) · Nano Letters · doi:10.1021/nl802810g · Cited by 647
Organic Mixed‐Valence Compounds: A Playground for Electrons and Holes
Heckmann, A., & Lambert, C. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201100944 · Cited by 560
What's new in stable radical chemistry?
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Metadata
- Authors
- Itkis, M. E., Chi, X., Cordes, A. W., & Haddon, R. C.
- Venue
- Science
- Published
- 2002-05-24
- Volume
- 296
- Issue
- 5572
- Pages
- 1443-1445
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2087497057
- Cited by
- 592
- References
- 5
- FWCI
- 20.82
- Type
- journal article
- Language
- en
- Open access
- closed
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