The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Giant Supramolecular Liquid Crystal Lattice
Abstract
Self-organized supramolecular organic nanostructures have potential applications that include molecular electronics, photonics, and precursors for nanoporous catalysts. Accordingly, understanding how self-assembly is controlled by molecular architecture will enable the design of increasingly complex structures. We report a liquid crystal (LC) phase with a tetragonal three-dimensional unit cell containing 30 globular supramolecular dendrimers, each of which is self-assembled from 12 dendron (tree-like) molecules, for the compounds described here. The present structure is one of the most complex LC phases yet discovered. A model explaining how spatial arrangement of self-assembled dendritic aggregates depends on molecular architecture and temperature is proposed.
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Cites
The Physics of Block Copolymers
Hamley, I. W. (1998) · doi:10.1093/oso/9780198502180.001.0001 · Cited by 1,913
Cited by
Functional Liquid‐Crystalline Assemblies: Self‐Organized Soft Materials
Kato, T., Mizoshita, N., & Kishimoto, K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200501384 · Cited by 1,545
Tethered Nano Building Blocks: Toward a Conceptual Framework for Nanoparticle Self-Assembly
Zhang, Horsch, M. A., Lamm, M. H., & Glotzer, S. C. (2003) · Nano Letters · doi:10.1021/nl034454g · Cited by 320
From structure to function via complex supramolecular dendrimer systems
Sun, H.-J., Zhang, S., & Percec, V. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00249k · Cited by 304
Self-citationThermal processing of diblock copolymer melts mimics metallurgy
Kim, K., Schulze, M. W., Arora, A., Lewis, R. M., Hillmyer, M. A., Dorfman, K. D., & Bates, F. S. (2017) · Science · doi:10.1126/science.aam7212 · Cited by 295
Fluctuations, Order, and Disorder in Short Diblock Copolymers
Lee, S., Gillard, T. M., & Bates, F. S. (2013) · AIChE Journal · doi:10.1002/aic.14023 · Cited by 100
Metadata
- Authors
- Ungar, G., Liu, Y., Zeng, X., Percec, V., & Cho, W.-D.
- Venue
- Science
- Published
- 2003-02-21
- Volume
- 299
- Issue
- 5610
- Pages
- 1208-1211
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1971885698
- Cited by
- 452
- References
- 1
- FWCI
- 19.99
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ungar, G., Liu, Y., Zeng, X., Percec, V., & Cho, W.-D. (2003). Giant Supramolecular Liquid Crystal Lattice. Science. https://doi.org/10.1126/science.1078849
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
