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Epitaxial BiFeO 3 Multiferroic Thin Film Heterostructures

Open access
Wang, J., Neaton, J. B., Zheng, H., Nagarajan, V., Ogale, S. B., Liu, B., Viehland, D., Vaithyanathan, V., Schlom, D. G., Waghmare, U. V., Spaldin, N. A., Rabe, K. M., Wuttig, M., Ramesh, R.·2003·Science

Abstract

Enhancement of polarization and related properties in heteroepitaxially constrained thin films of the ferroelectromagnet, BiFeO 3 , is reported. Structure analysis indicates that the crystal structure of film is monoclinic in contrast to bulk, which is rhombohedral. The films display a room-temperature spontaneous polarization (50 to 60 microcoulombs per square centimeter) almost an order of magnitude higher than that of the bulk (6.1 microcoulombs per square centimeter). The observed enhancement is corroborated by first-principles calculations and found to originate from a high sensitivity of the polarization to small changes in lattice parameters. The films also exhibit enhanced thickness-dependent magnetism compared with the bulk. These enhanced and combined functional responses in thin film form present an opportunity to create and implement thin film devices that actively couple the magnetic and ferroelectric order parameters.

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Crossref · 10.1126/science.1080615

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Metadata

Authors
Wang, J., Neaton, J. B., Zheng, H., Nagarajan, V., Ogale, S. B., Liu, B., Viehland, D., Vaithyanathan, V., Schlom, D. G., Waghmare, U. V., Spaldin, N. A., Rabe, K. M., Wuttig, M., & Ramesh, R.
Venue
Science
Published
2003-03-14
Volume
299
Issue
5613
Pages
1719-1722
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2130156865
Cited by
6,217
References
2
FWCI
61.81
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Epitaxial BiFeO 3 Multiferroic Thin Film Heterostructures. https://app.cochat.ai/papers/10.1126/science.1080615
The paper
Wang, J., Neaton, J. B., Zheng, H., Nagarajan, V., Ogale, S. B., Liu, B., Viehland, D., Vaithyanathan, V., Schlom, D. G., Waghmare, U. V., Spaldin, N. A., Rabe, K. M., Wuttig, M., & Ramesh, R. (2003). Epitaxial BiFeO 3 Multiferroic Thin Film Heterostructures. Science. https://doi.org/10.1126/science.1080615

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.