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Superlattices of Iron Nanocubes Synthesized from Fe[N(SiMe 3 ) 2 ] 2
Abstract
The reaction of the metal-organic precursor Fe[N(SiMe 3 ) 2 ] 2 with H 2 in the presence of a long-chain acid and a long-chain amine in various proportions produces monodisperse zerovalent iron nanoparticles. These Fe particles display magnetic properties that match those of bulk iron as evidenced by magnetic and Mössbauer measurements. The nanoparticles adopt a cubic shape with edges of 7 nanometers and are incorporated into extended crystalline superlattices containing nanocubes in close proximity and with their crystallographic axes aligned. These superlattices are formed in solution, precipitate in high yield, and may be redissolved and redeposited as two-dimensional arrays.
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Citations
Cites
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices
Sun, S., Murray, C. B., Weller, D., Folks, L., & Moser, A. (2000) · Science · doi:10.1126/science.287.5460.1989 · Cited by 6,137
Cited by
Chemistry and Properties of Nanocrystals of Different Shapes
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702
Ultra-large-scale syntheses of monodisperse nanocrystals
Park, J., An, K., Hwang, Y., Park, J.-G., Noh, H.-J., Kim, J.-Y., Park, J.-H., Hwang, N.-M., & Hyeon, T. (2004) · Nature Materials · doi:10.1038/nmat1251 · Cited by 4,076
Ferrite-based magnetic nanofluids used in hyperthermia applications
Sharifi, I., Shokrollahi, H., & Amiri, S. (2012) · Journal of Magnetism and Magnetic Materials · doi:10.1016/j.jmmm.2011.10.017 · Cited by 759
Organic Phase Syntheses of Magnetic Nanoparticles and Their Applications
Wu, L., Mendoza-Garcia, A., Li, Q., & Sun, S. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00687 · Cited by 601
Metadata
- Authors
- Dumestre, F., Chaudret, B., Amiens, C., Renaud, P., & Fejes, P.
- Venue
- Science
- Published
- 2004-02-06
- Volume
- 303
- Issue
- 5659
- Pages
- 821-823
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1991748141
- Cited by
- 545
- References
- 1
- FWCI
- 33.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dumestre, F., Chaudret, B., Amiens, C., Renaud, P., & Fejes, P. (2004). Superlattices of Iron Nanocubes Synthesized from Fe[N(SiMe 3 ) 2 ] 2. Science. https://doi.org/10.1126/science.1092641
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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