The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Renewable Hydrogen from Ethanol by Autothermal Reforming
Abstract
Ethanol and ethanol-water mixtures were converted directly into H 2 with ∼100% selectivity and >95% conversion by catalytic partial oxidation, with a residence time on rhodium-ceria catalysts of <10 milliseconds.Rapid vaporization and mixing with air with an automotive fuel injector were performed at temperatures sufficiently low and times sufficiently fast that homogeneous reactions producing carbon, acetaldehyde, ethylene, and total combustion products can be minimized.This process has great potential for low-cost H 2 generation in fuel cells for small portable applications where liquid fuel storage is essential and where systems must be small, simple, and robust.
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Citations
Cites
Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water
Cortright, R. D., Davda, R. R., & Dumesic, J. A. (2002) · Nature · doi:10.1038/nature01009 · Cited by 2,128
Raney Ni-Sn Catalyst for H 2 Production from Biomass-Derived Hydrocarbons
Huber, G. W., Shabaker, J. W., & Dumesic, J. A. (2003) · Science · doi:10.1126/science.1085597 · Cited by 936
Liguras, D. K., Kondarides, D. I., & Verykios, X. E. (2003) · Applied Catalysis B: Environmental · doi:10.1016/s0926-3373(02)00327-2 · Cited by 718
Self-citationA comparative study of fuels for on-board hydrogen production for fuel-cell-powered automobiles
Brown, L. F. (2001) · International Journal of Hydrogen Energy · doi:10.1016/s0360-3199(00)00092-6 · Cited by 621
Electrocatalytic oxidation of aliphatic alcohols: Application to the direct alcohol fuel cell (DAFC)
Lamy, C., Belgsir, E. M., & Léger, J.-M. (2001) · Journal of Applied Electrochemistry · doi:10.1023/a:1017587310150 · Cited by 589
The Energy Balance of Corn Ethanol: An Update
USDOE Office of Energy Efficiency and Renewable Energy (EERE), O. O. S. T. B. T. O. (., Shapouri, H., US Department of Energy (USDOE), W., Duffield, J., & Wang, M. (2002) · doi:10.2172/1218357 · Cited by 554
Garcia, L., French, R. J., Czernik, S., & Chornet, E. (2000) · Applied Catalysis A General · doi:10.1016/s0926-860x(00)00440-3 · Cited by 530
Production of hydrogen for fuel cells by reformation of biomass-derived ethanol
Fatsikostas, A. N., Kondarides, D. I., & Verykios, X. E. (2002) · Catalysis Today · doi:10.1016/s0920-5861(02)00057-3 · Cited by 472
Self-citationConversion of hydrocarbons and alcohols for fuel cells
Rostrup-Nielsen, J. R. (2001) · Physical Chemistry Chemical Physics · doi:10.1039/b004660o · Cited by 251
Cited by
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
Montini, T., Melchionna, M., Monai, M., & Fornasiero, P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00603 · Cited by 2,766
Catalysis by Supported Single Metal Atoms
Liu, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b01534 · Cited by 1,331
Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding
Farmer, J. A., & Campbell, C. T. (2010) · Science · doi:10.1126/science.1191778 · Cited by 964
Raman Spectra of Polycrystalline CeO2: A Density Functional Theory Study
Schilling, C., Hofmann, A., Hess, C., & Ganduglia-Pirovano, M. V. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b06643 · Cited by 513
Water gas shift reaction for hydrogen production and carbon dioxide capture: A review
Chen, W.-H., & Chen, C.-Y. (2020) · Applied Energy · doi:10.1016/j.apenergy.2019.114078 · Cited by 486
Metadata
- Authors
- Deluga, G. A., Salge, J. R., Schmidt, L. D., & Verykios, X. E.
- Venue
- Science
- Published
- 2004-02-13
- Volume
- 303
- Issue
- 5660
- Pages
- 993-997
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1969104275
- Cited by
- 992
- References
- 9
- FWCI
- 23.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Renewable Hydrogen from Ethanol by Autothermal Reforming. https://app.cochat.ai/papers/10.1126/science.1093045
- The paper
- Deluga, G. A., Salge, J. R., Schmidt, L. D., & Verykios, X. E. (2004). Renewable Hydrogen from Ethanol by Autothermal Reforming. Science. https://doi.org/10.1126/science.1093045
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
