The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Multicompartment Micelles from ABC Miktoarm Stars in Water
Abstract
By combining three mutually immiscible polymeric components in a mixed-arm star block terpolymer architecture, we have observed the formation of a previously unknown class of multicompartment micelles in dilute aqueous solution. Connection of water-soluble poly(ethylene oxide) and two hydrophobic but immiscible components (a polymeric hydrocarbon and a perfluorinated polyether) at a common junction leads to molecular frustration when dispersed in aqueous solution. The incompatible hydrophobic blocks form cores that are protected from the water by the poly(ethylene oxide) blocks, but both are forced to make contact with the poly(ethylene oxide) by virtue of the chain architecture. The structures that emerge depend on the relative lengths of the blocks and can be tuned from discrete multicompartment micelles to extended wormlike structures with segmented cores.
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Cites
The Physics of Block Copolymers
Hamley, I. W. (1998) · doi:10.1093/oso/9780198502180.001.0001 · Cited by 1,913
On the origins of morphological complexity in block copolymer surfactants
Jain, S., & Bates, F. S. (2003) · Science · doi:10.1126/science.1082193 · Cited by 1,217
Cited by
Physical approaches to biomaterial design
Mitragotri, S., & Lahann, J. (2009) · Nature Materials · doi:10.1038/nmat2344 · Cited by 1,445
Block Copolymer Assembly via Kinetic Control
Cui, H., Chen, Z., Zhong, S., Wooley, K. L., & Pochan, D. J. (2007) · Science · doi:10.1126/science.1141768 · Cited by 1,049
Miktoarm star polymers: advances in synthesis, self-assembly, and applications
Khanna, K., Varshney, S., & Kakkar, A. (2010) · Polymer Chemistry · doi:10.1039/c0py00082e · Cited by 329
Fluoropolymers in Biomedical Applications: State-of-the-Art and Future Perspectives
Lv, J., & Cheng, Y. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00258e · Cited by 316
Spherical polyelectrolyte brushes
Ballauff, M. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.05.002 · Cited by 313
Metadata
- Authors
- Li, Z., Kesselman, E., Talmon, Y., Hillmyer, M. A., & Lodge, T. P.
- Venue
- Science
- Published
- 2004-10
- Volume
- 306
- Issue
- 5693
- Pages
- 98-101
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2142234529
- Cited by
- 947
- References
- 2
- FWCI
- 21.61
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, Z., Kesselman, E., Talmon, Y., Hillmyer, M. A., & Lodge, T. P. (2004). Multicompartment Micelles from ABC Miktoarm Stars in Water. Science. https://doi.org/10.1126/science.1103350
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