The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO 2 Catalysts
Abstract
The oxidation of alcohols to aldehydes with O 2 in place of stoichiometric oxygen donors is a crucial process for the synthesis of fine chemicals. However, the catalysts that have been identified so far are relatively inactive with primary alkyl alcohols. We showed that Au/Pd-TiO 2 catalysts give very high turnover frequencies (up to 270,000 turnovers per hour) for the oxidation of alcohols, including primary alkyl alcohols. The addition of Au to Pd nanocrystals improved the overall selectivity and, using scanning transmission electron microscopy combined with x-ray photoelectron spectroscopy, we showed that the Au-Pd nanocrystals were made up of a Au-rich core with a Pd-rich shell, indicating that the Au electronically influences the catalytic properties of Pd.
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Cites
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A Collaborative Effect between Gold and a Support Induces the Selective Oxidation of Alcohols
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Gold on Carbon as a New Catalyst for Selective Liquid Phase Oxidation of Diols
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Direct synthesis of hydrogen peroxide from H2 and O2 using TiO2-supported Au–Pd catalysts
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Self-citationPorta, F., & Prati, L. (2004) · Journal of Catalysis · doi:10.1016/j.jcat.2004.03.009 · Cited by 377
Direct synthesis of hydrogen peroxide from H2 and O2 using Pd and Au catalysts
Landon, P., Collier, P. J., Carley, A. F., Chadwick, D., Papworth, A. J., Burrows, A., Kiely, C. J., & Hutchings, G. J. (2003) · Physical Chemistry Chemical Physics · doi:10.1039/b211338b · Cited by 363
Self-citationDirect synthesis of hydrogen peroxide from H2 and O2 using Au–Pd/Fe2O3 catalysts
Edwards, J. K., Solsona, B., Landon, P., Carley, A. F., Herzing, A. A., Watanabe, M., Kiely, C. J., & Hutchings, G. J. (2005) · Journal of Materials Chemistry · doi:10.1039/b509542e · Cited by 183
Self-citationSchultz, M. J., Adler, R. S., Zierkiewicz, W., et al. (2005) · Journal of the American Chemical Society · doi:10.1021/ja050949r · Cited by 127
New Au(0) Sols as Precursors for Heterogeneous Liquid-Phase Oxidation Catalysts
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Cited by
Hashmi, A. S. K., & Hutchings, G. J. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602454 · Cited by 3,423
Self-citationSupported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
Herzing, A. A., Kiely, C. J., Carley, A. F., Landon, P., & Hutchings, G. J. (2008) · Science · doi:10.1126/science.1159639 · Cited by 1,530
Self-citationTitanium Dioxide Crystals with Tailored Facets
Liu, G., Yang, H. G., Pan, J., Yang, Y. Q., Lu, G. Q. (., & Cheng, H.-M. (2014) · Chemical Reviews · doi:10.1021/cr400621z · Cited by 1,084
Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 689
Metadata
- Authors
- Enache, D. I., Edwards, J. K., Landon, P., Solsona-Espriu, B., Carley, A. F., Herzing, A. A., Watanabe, M., Kiely, C. J., Knight, D. W., & Hutchings, G. J.
- Venue
- Science
- Published
- 2006-01-20
- Volume
- 311
- Issue
- 5759
- Pages
- 362-365
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2029842534
- Cited by
- 2,106
- References
- 10
- FWCI
- 63.37
- Type
- journal article
- Language
- en
- Open access
- closed
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- Enache, D. I., Edwards, J. K., Landon, P., Solsona-Espriu, B., Carley, A. F., Herzing, A. A., Watanabe, M., Kiely, C. J., Knight, D. W., & Hutchings, G. J. (2006). Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO 2 Catalysts. Science. https://doi.org/10.1126/science.1120560
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