The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
An Octahedral Coordination Complex of Iron(VI)
Abstract
The hexavalent state, considered to be the highest oxidation level accessible for iron, has previously been found only in the tetrahedral ferrate dianion, FeO 4 2– . We report the photochemical synthesis of another Fe(VI) compound, an octahedrally coordinated dication bearing a terminal nitrido ligand. Mössbauer and x-ray absorption spectra, supported by density functional theory, are consistent with the octahedral structure having an Fe N triple bond of 1.57 angstroms and a singlet \batchmode \documentclass[fleqn,10pt,legalpaper]{article} \usepackage{amssymb} \usepackage{amsfonts} \usepackage{amsmath} \pagestyle{empty} \begin{document} \(\mathrm{d}_{xy}^{2}\) \end{document} ground electronic configuration. The compound is stable at 77 kelvin and yields a high-spin Fe(III) species upon warming.
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Cited by
Density functional theory for transition metals and transition metal chemistry
Cramer, C. J., & Truhlar, D. G. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b907148b · Cited by 1,648
Neese, F. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2008.05.014 · Cited by 1,071
Self-citationFürstner, A. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00272 · Cited by 746
Slow Magnetic Relaxation in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes
Harman, W. H., Harris, T. D., Freedman, D. E., Fong, H., Chang, A., Rinehart, J. D., Ozarowski, A., Sougrati, M. T., Grandjean, F., Long, G. J., et al. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105291x · Cited by 342
TERMINAL NITRIDO AND IMIDO COMPLEXES OF THE LATE TRANSITION METALS
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Self-citation
Metadata
- Authors
- Berry, J. F., Bill, E., Bothe, E., George, S. D., Mienert, B., Neese, F., & Wieghardt, K.
- Venue
- Science
- Published
- 2006-06-30
- Volume
- 312
- Issue
- 5782
- Pages
- 1937-1941
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2053472539
- Cited by
- 321
- References
- 26
- FWCI
- 17.02
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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