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Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-Oxidation Activity
Abstract
The shapes of noble metal nanocrystals (NCs) are usually defined by polyhedra that are enclosed by {111} and {100} facets, such as cubes, tetrahedra, and octahedra. Platinum NCs of unusual tetrahexahedral (THH) shape were prepared at high yield by an electrochemical treatment of Pt nanospheres supported on glassy carbon by a square-wave potential. The single-crystal THH NC is enclosed by 24 high-index facets such as {730}, {210}, and/or {520} surfaces that have a large density of atomic steps and dangling bonds. These high-energy surfaces are stable thermally (to 800°C) and chemically and exhibit much enhanced (up to 400%) catalytic activity for equivalent Pt surface areas for electro-oxidation of small organic fuels such as formic acid and ethanol.
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“The tetrahexahedral (THH) shape nanocrystal is bounded by 24 facets of high-index planes (730) and vicinal planes such as (210) and (310).57”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [57]
In the citing paper
“Therefore, the dominant facets of the THH Pt nanocrystals are (730) with contributions from ( 210), (310), and (520).”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [57]
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Metadata
- Authors
- Tian, N., Zhou, Z.-Y., Sun, S.-G., Ding, Y., & Wang, Z. L.
- Affiliations
- Georgia Institute of Technology (US)
- Corresponding author
- Sun, Shi-Gang
- Wang, Zhong Lin
- Venue
- Science
- Published
- 2007-05-04
- Volume
- 316
- Issue
- 5825
- Pages
- 732-735
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2061820211
- Cited by
- 3,073
- References
- 30
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- FWCI
- 105.43
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
- Keywords
- platinum nanocrystals, high-index facets, electrochemical oxidation, formic acid oxidation, ethanol oxidation, electrocatalysis, nanocrystal synthesis, single-crystal nanocrystals
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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