The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Measurement of the Distribution of Site Enhancements in Surface-Enhanced Raman Scattering
Abstract
On nanotextured noble-metal surfaces, surface-enhanced Raman scattering (SERS) is observed, where Raman scattering is enhanced by a factor, Ḡ , that is frequently about one million, but underlying the factor Ḡ is a broad distribution of local enhancement factors, η. We have measured this distribution for benzenethiolate molecules on a 330-nanometer silver-coated nanosphere lattice using incident light of wavelength 532 nanometers. A series of laser pulses with increasing electric fields burned away molecules at sites with progressively decreasing electromagnetic enhancement factors. The enhancement distribution P (η) d η was found to be a power law proportional to (η) –1.75 , with minimum and maximum values of 2.8 × 10 4 and 4.1 × 10 10 , respectively. The hottest sites (η >10 9 ) account for just 63 in 1,000,000 of the total but contribute 24% to the overall SERS intensity.
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Cites
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Cited by
Zhang, J., Li, Y., Zhang, X., & Yang, B. (2010) · Advanced Materials · doi:10.1002/adma.201000755 · Cited by 649
Theoretical Studies of Plasmonics using Electronic Structure Methods
Morton, S. M., Silverstein, D. W., & Jensen, L. (2011) · Chemical Reviews · doi:10.1021/cr100265f · Cited by 474
Large-Scale Hot Spot Engineering for Quantitative SERS at the Single-Molecule Scale
Chen, H.-Y., Lin, M.-H., Wang, C.-Y., Chang, Y.-M., & Gwo, S. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09111 · Cited by 426
Unraveling the origin of chirality from plasmonic nanoparticle-protein complexes
Zhang, Q., Hernandez, T., Smith, K. W., Hosseini Jebeli, S. A., Dai, A. X., Warning, L., Baiyasi, R., McCarthy, L. A., Guo, H., Chen, D.-H., et al. (2019) · Science · doi:10.1126/science.aax5415 · Cited by 336
Persistent misconceptions regarding SERS
Moskovits, M. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp44030j · Cited by 295
Metadata
- Authors
- Fang, Y., Seong, N.-H., & Dlott, D. D.
- Venue
- Science
- Published
- 2008-07-18
- Volume
- 321
- Issue
- 5887
- Pages
- 388-392
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2009658139
- Cited by
- 1,146
- References
- 3
- FWCI
- 21.15
- Type
- journal article
- Language
- en
- Open access
- closed
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