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A Strain-Driven Morphotropic Phase Boundary in BiFeO 3
Abstract
Biffed into Shape: BiFeO 3 is known to have a very large ferroelectric polarization. Although the bulk ground state is rhombohedral (with the electrical polarization along the [111] direction), in thin films and under epitaxial strain, the material can be tetragonally distorted (polarization along [001]). Zeches et al. (p. 977 ) show that under compressive strain, these films are monoclinic, a phase that is highly stable because it comprises the same symmetry as the monoclinic phase which has been reported at the so-called morphotropic phase boundaries in technologically important ferroelectrics. This work offers the possibility of obtaining large piezoelectric responses in lead-free systems.
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Cites
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Cited by
BiFeO 3 Ceramics: Processing, Electrical, and Electromechanical Properties
Rojac, T., Bencan, A., Malic, B., Tutuncu, G., Jones, J. L., Daniels, J. E., & Damjanovic, D. (2014) · Journal of the American Ceramic Society · doi:10.1111/jace.12982 · Cited by 482
Stress-inducedR−MA−MC−Tsymmetry changes in BiFeO3films
Christen, H. M., Nam, J. H., Kim, H. S., Hatt, A. J., & Spaldin, N. A. (2011) · Physical Review B · doi:10.1103/physrevb.83.144107 · Cited by 276
Self-citationStructural and Photophysical Properties of Methylammonium Lead Tribromide (MAPbBr3) Single Crystals
Wang, K.-H., Li, L.-C., Shellaiah, M., & Wen Sun, K. (2017) · Scientific Reports · doi:10.1038/s41598-017-13571-1 · Cited by 271
Fluorite-structure antiferroelectrics
Park, M. H., & Hwang, C. S. (2019) · Reports on Progress in Physics · doi:10.1088/1361-6633/ab49d6 · Cited by 69
Metadata
- Authors
- Zeches, R. J., Rossell, M. D., Zhang, J. X., Hatt, A. J., He, Q., Yang, C.-H., Kumar, A., Wang, C. H., Melville, A., Adamo, C., Sheng, G., Chu, Y.-H., Ihlefeld, J. F., Erni, R., Ederer, C., Gopalan, V., Chen, L. Q., Schlom, D. G., Spaldin, N. A., Martin, L. W., & Ramesh, R.
- Venue
- Science
- Published
- 2009-11-13
- Volume
- 326
- Issue
- 5955
- Pages
- 977-980
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1980425760
- Cited by
- 1,260
- References
- 1
- FWCI
- 32.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Zeches, R. J., Rossell, M. D., Zhang, J. X., Hatt, A. J., He, Q., Yang, C.-H., Kumar, A., Wang, C. H., Melville, A., Adamo, C., Sheng, G., Chu, Y.-H., Ihlefeld, J. F., Erni, R., Ederer, C., Gopalan, V., Chen, L. Q., Schlom, D. G., Spaldin, N. A., . . . Ramesh, R. (2009). A Strain-Driven Morphotropic Phase Boundary in BiFeO 3. Science. https://doi.org/10.1126/science.1177046
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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