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Energy-Conversion Properties of Vapor-Liquid-Solid–Grown Silicon Wire-Array Photocathodes

Boettcher, Shannon W., Spurgeon, Joshua M., Putnam, Morgan C., Warren, Emily L., Turner-Evans, Daniel B., Kelzenberg, Michael D., Maiolo, James R., Atwater, Harry A., Lewis, Nathan S.·2010·Science

Abstract

Silicon Microwires as Photocathodes: Solar hydrogen generation will require the development of photocathodes with high surface area, durability, and efficiency. Silicon microwire arrays, which allow for greater light penetration, could achieve this goal if the carrier mobilities are sufficiently high so that surface reactions occur before charges recombine. Boettcher et al. (p. 185 ) report the electronic properties on positively doped silicon microwire arrays that were grown with copper catalysts and used in a methyl viologen redox system. Although equivalent efficiencies for normal solar fluxes were only 2 to 3%, the high internal efficiencies and low use of the available optical flux suggest that further improvements are possible.

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Metadata

Authors
Boettcher, S. W., Spurgeon, J. M., Putnam, M. C., Warren, E. L., Turner-Evans, D. B., Kelzenberg, M. D., Maiolo, J. R., Atwater, H. A., & Lewis, N. S.
Venue
Science
Published
2010-01-08
Volume
327
Issue
5962
Pages
185-187
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2000430472
Cited by
516
References
0
FWCI
35.86
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Energy-Conversion Properties of Vapor-Liquid-Solid–Grown Silicon Wire-Array Photocathodes. https://app.cochat.ai/papers/10.1126/science.1180783
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Boettcher, S. W., Spurgeon, J. M., Putnam, M. C., Warren, E. L., Turner-Evans, D. B., Kelzenberg, M. D., Maiolo, J. R., Atwater, H. A., & Lewis, N. S. (2010). Energy-Conversion Properties of Vapor-Liquid-Solid–Grown Silicon Wire-Array Photocathodes. Science. https://doi.org/10.1126/science.1180783

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