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Energy-Conversion Properties of Vapor-Liquid-Solid–Grown Silicon Wire-Array Photocathodes
Abstract
Silicon Microwires as Photocathodes: Solar hydrogen generation will require the development of photocathodes with high surface area, durability, and efficiency. Silicon microwire arrays, which allow for greater light penetration, could achieve this goal if the carrier mobilities are sufficiently high so that surface reactions occur before charges recombine. Boettcher et al. (p. 185 ) report the electronic properties on positively doped silicon microwire arrays that were grown with copper catalysts and used in a methyl viologen redox system. Although equivalent efficiencies for normal solar fluxes were only 2 to 3%, the high internal efficiencies and low use of the available optical flux suggest that further improvements are possible.
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Cited by
Laursen, A. B., Kegnæs, S., Dahl, S., & Chorkendorff, I. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02618j · Cited by 1,348
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153
Benck, J. D., Chen, Z., Kuritzky, L. Y., Forman, A. J., & Jaramillo, T. F. (2012) · ACS Catalysis · doi:10.1021/cs300451q · Cited by 1,091
Woodward, A. N., Kolesar, J. M., Hall, S. R., Saleh, N.-A., Jones, D. S., & Walter, M. G. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01005 · Cited by 325
Metadata
- Authors
- Boettcher, S. W., Spurgeon, J. M., Putnam, M. C., Warren, E. L., Turner-Evans, D. B., Kelzenberg, M. D., Maiolo, J. R., Atwater, H. A., & Lewis, N. S.
- Venue
- Science
- Published
- 2010-01-08
- Volume
- 327
- Issue
- 5962
- Pages
- 185-187
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2000430472
- Cited by
- 516
- References
- 0
- FWCI
- 35.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- Boettcher, S. W., Spurgeon, J. M., Putnam, M. C., Warren, E. L., Turner-Evans, D. B., Kelzenberg, M. D., Maiolo, J. R., Atwater, H. A., & Lewis, N. S. (2010). Energy-Conversion Properties of Vapor-Liquid-Solid–Grown Silicon Wire-Array Photocathodes. Science. https://doi.org/10.1126/science.1180783
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