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Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
Abstract
Many Mixed Linkers in MOFs: Crystallization can separate different molecules because different molecules cannot generally be accommodated equally well in the same crystal lattice. However, in metal-organic framework (MOF) compounds, the organic linkers do not pack closely to other parts of the lattice, so it may be possible to mix several linkers that are derivatives of a parent compound with the same end groups. Deng et al. (p. 846 ) show that zinc-based MOFs can be made that mix 1,4-benzenedicarboxylate and up to eight of its derivatives in a random fashion. The effects of such mixing on porosity and absorption characteristics is nonlinear; in one case, a mixed-linker compound was four times better for selecting CO 2 versus CO compared with the best MOF bearing only one of the component linkers.
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Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
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Cited by
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Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
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MacDowell, N., Florin, N., Buchard, A., Hallett, J., Galindo, A., Jackson, G., Adjiman, C. S., Williams, C. K., Shah, N., & Fennell, P. (2010) · Energy & Environmental Science · doi:10.1039/c004106h · Cited by 1,636
Large-scale screening of hypothetical metal–organic frameworks
Wilmer, C. E., Leaf, M., Lee, C. Y., Farha, O. K., Hauser, B. G., Hupp, J. T., & Snurr, R. Q. (2012) · Nature Chemistry · doi:10.1038/nchem.1192 · Cited by 1,439
Luminescent sensors based on metal-organic frameworks
Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Yu, X., Tang, Z., Sun, D., Ouyang, L., & Zhu, M. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.03.001 · Cited by 716
Metadata
- Authors
- Deng, H., Doonan, C. J., Furukawa, H., Ferreira, R. B., Towne, J., Knobler, C. B., Wang, B., & Yaghi, O. M.
- Venue
- Science
- Published
- 2010-02-12
- Volume
- 327
- Issue
- 5967
- Pages
- 846-850
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2072170322
- Cited by
- 1,917
- References
- 1
- FWCI
- 71.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Deng, H., Doonan, C. J., Furukawa, H., Ferreira, R. B., Towne, J., Knobler, C. B., Wang, B., & Yaghi, O. M. (2010). Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks. Science. https://doi.org/10.1126/science.1181761
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