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Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes
Abstract
An Iron Hand for Silicon: Carbon-silicon bonds are integral to the structure of the silicone materials widely used in adhesives, cosmetics, and numerous other industrial and consumer products. Generally, platinum-based catalysts have performed best in the hydrosilylation reactions that form these bonds, but the expense of the precious metal and, in some cases, by-product formation have motivated a search for alternatives. Tondreau et al. (p. 567 ) now show that a class of iron compounds readily catalyzes hydrosilylation of certain commercially important substrates with rates and selectivities comparable to, or even exceeding, those associated with platinum.
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Citations
Cited by
Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
Obligacion, J. V., & Chirik, P. J. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-018-0001-2 · Cited by 893
Self-citationDelle Chiaie, K. R., Biernesser, A. B., Ortuño, M. A., Dereli, B., Iovan, D. A., Wilding, M. J. T., Li, B., Cramer, C. J., & Byers, J. A. (2017) · Dalton Transactions · doi:10.1039/c7dt03067c · Cited by 48
Metadata
- Authors
- Tondreau, A. M., Atienza, C. C. H., Weller, K. J., Nye, S. A., Lewis, K. M., Delis, J. G. P., & Chirik, P. J.
- Venue
- Science
- Published
- 2012-02-03
- Volume
- 335
- Issue
- 6068
- Pages
- 567-570
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2067886511
- Cited by
- 556
- References
- 0
- FWCI
- 22.46
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes. https://app.cochat.ai/papers/10.1126/science.1214451
- The paper
- Tondreau, A. M., Atienza, C. C. H., Weller, K. J., Nye, S. A., Lewis, K. M., Delis, J. G. P., & Chirik, P. J. (2012). Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes. Science. https://doi.org/10.1126/science.1214451
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
