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Capturing Ultrasmall EMT Zeolite from Template-Free Systems
Open accessAbstract
Controlling Zeolite Nucleation: Small zeolite crystals are of increasing interest as catalysts and for membrane separations because they allow the high selectivity of their cages to be exploited while minimizing the kinetic limitations caused by diffusion. Ng et al. (p. 70 , published online 8 December) synthesized ultrasmall crystals (6 to 15 nanometers) of the EMT zeolite, which has a low framework density and good catalytic properties for hydrocarbon “cracking” (conversion of a large hydrocarbon to smaller ones). The synthesis of EMT has normally required expensive organic templates that limit its industrial use. Careful control of the synthesis conditions, such as ratios of reactants and short bursts of microwave heating, allowed small EMT crystals to nucleate and avoid formation of zeolites with closely related structures.
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Ordered porous materials for emerging applications
Davis, M. E. (2002) · Nature · doi:10.1038/nature00785 · Cited by 5,308
Cited by
Hierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Green Routes for Synthesis of Zeolites
Meng, X., & Xiao, F.-S. (2014) · Chemical Reviews · doi:10.1021/cr4001513 · Cited by 635
New Stories of Zeolite Structures: Their Descriptions, Determinations, Predictions, and Evaluations
Li, Y., & Yu, J. (2014) · Chemical Reviews · doi:10.1021/cr500010r · Cited by 603
New trends in tailoring active sites in zeolite-based catalysts
Shamzhy, M., Opanasenko, M., Concepción, P., & Martínez, A. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00887f · Cited by 508
Template-free nanosized faujasite-type zeolites
Awala, H., Gilson, J.-P., Retoux, R., Boullay, P., Goupil, J.-M., Valtchev, V., & Mintova, S. (2015) · Nature Materials · doi:10.1038/nmat4173 · Cited by 484
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Metadata
- Authors
- Ng, E.-P., Chateigner, D., Bein, T., Valtchev, V., & Mintova, S.
- Venue
- Science
- Published
- 2012-01-06
- Volume
- 335
- Issue
- 6064
- Pages
- 70-73
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2067963013
- Cited by
- 293
- References
- 1
- FWCI
- 10.22
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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