Template-free nanosized faujasite-type zeolites
Abstract
Nanosized faujasite (FAU) crystals have great potential as catalysts or adsorbents to more efficiently process present and forthcoming synthetic and renewable feedstocks in oil refining, petrochemistry and fine chemistry. Here, we report the rational design of template-free nanosized FAU zeolites with exceptional properties, including extremely small crystallites (10-15 nm) with a narrow particle size distribution, high crystalline yields (above 80%), micropore volumes (0.30 cm(3) g(-1)) comparable to their conventional counterparts (micrometre-sized crystals), Si/Al ratios adjustable between 1.1 and 2.1 (zeolites X or Y) and excellent thermal stability leading to superior catalytic performance in the dealkylation of a bulky molecule, 1,3,5-triisopropylbenzene, probing sites mostly located on the external surface of the nanosized crystals. Another important feature is their excellent colloidal stability, which facilitates a uniform dispersion on supports for applications in catalysis, sorption and thin-to-thick coatings.
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The reduction of average crystal size of a zeolite is mostly done directly by hydrothermal synthesis promoting nucleation versus crystal growth.
“The reduction of average crystal size of a zeolite is mostly done directly by hydrothermal synthesis promoting nucleation versus crystal growth,99,134−138 although other nonconventional methods have been applied as well.139”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [135]
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Insights into the Organotemplate-Free Synthesis of Zeolite Catalysts
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Make it clean, make it safe: A review on virus elimination via adsorption
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Zeolite Nanoparticles for Selective Sorption of Plasma Proteins
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Self-citationCore-shell and egg-shell zeolite catalysts for enhanced hydrocarbon processing
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Machine learning-assisted crystal engineering of a zeolite
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Self-citationProbing the Brønsted Acidity of the External Surface of Faujasite‐Type Zeolites
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Flexible Template-Free RHO Nanosized Zeolite for Selective CO 2 Adsorption
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Self-citationSynthesis of Mesoporous Zeolites and Their Opportunities in Heterogeneous Catalysis
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Nanoscale Control of Homoepitaxial Growth on a Two‐Dimensional Zeolite
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Nanosized inorganic porous materials: fabrication, modification and application
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Self-citationSupported Embryonic Zeolites and their Use to Process Bulky Molecules
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Self-citationMolecular Modifiers Suppress Nonclassical Pathways of Zeolite Crystallization
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SDA-Free Hydrothermal Synthesis of High-Silica Ultra-nanosized Zeolite Y
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Crystal Engineering for Catalysis
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Self-citationDynamic adsorption of CO2 by CHA zeolites – Size matters
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Self-citationTemperature-regulated construction of hierarchical titanosilicate zeolites
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K-F zeolite nanocrystals synthesized from organic-template-free precursor mixture
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- Authors
- Awala, H., Gilson, J.-P., Retoux, R., Boullay, P., Goupil, J.-M., Valtchev, V., & Mintova, S.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Mintova, Svetlana
- Venue
- Nature Materials
- Published
- 2015-01-05
- Volume
- 14
- Issue
- 4
- Pages
- 447-451
- ISSN
- 1476-1122 (ISSN-L)
- 1476-4660
- OpenAlex
- W1994047443
- Cited by
- 484
- References
- 39
- Citations by year
- 2026: 20 · 2025: 41 · 2024: 51 · 2023: 42 · 2022: 40 · 2021: 45 · 2020: 56 · 2019: 40 · 2018: 50 · 2017: 42 · 2016: 38 · 2015: 19
- FWCI
- 20.40
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Nature Materials (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Environmental Science › Waste Management and Disposal › Chemical Synthesis and Characterization
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Keywords
- faujasite, nanosized zeolites, template-free synthesis, zeolite crystallization, Si/Al ratio, zeolite X, zeolite Y, thermal stability, dealkylation, 1,3,5-triisopropylbenzene, colloidal stability, particle size distribution, catalysts, adsorbents
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