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Exceptional Activity for Methane Combustion over Modular Pd@CeO 2 Subunits on Functionalized Al 2 O 3
Abstract
Addressing a Burning Issue: Complete combustion of methane is required in order to avoid the unproductive emission of this greenhouse gas into the atmosphere. Palladium catalysts can help to promote complete combustion, but high-temperature operating conditions also promote aggregation of catalyst particles (“sintering”) that lowers their surface area and overall activity. Cargnello et al. (p. 713 ; see the Perspective by Farrauto ) report that cerium oxide–coated Pd catalyst particles could be fully dispersed on an alumina surface prepared with a hydrophobic coating. This treatment resisted Pd sintering up to temperatures of 800°C, and also enabled complete combustion of methane to occur at temperatures as low as 400°C.
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Cited by
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
Montini, T., Melchionna, M., Monai, M., & Fornasiero, P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00603 · Cited by 2,766
Self-citationEncapsulated Metal Nanoparticles for Catalysis
Gao, C., Lyu, F., & Yin, Y. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00237 · Cited by 855
Ru/CeO2 Catalyst with Optimized CeO2 Support Morphology and Surface Facets for Propane Combustion
Wang, Z., Huang, Z., Brosnahan, J. T., Zhang, S., Guo, Y., Guo, Y., Wang, L., Wang, Y., & Zhan, W. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b01929 · Cited by 377
Metal/Oxide Interface Nanostructures Generated by Surface Segregation for Electrocatalysis
Weng, Z., Liu, W., Yin, L.-C., Fang, R., Li, M., Altman, E. I., Fan, Q., Li, F., Cheng, H.-M., & Wang, H. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b03709 · Cited by 278
Sintering-resistant Pt@CeO 2 nanoparticles for high-temperature oxidation catalysis
Lee, S., Seo, J., & Jung, W. (2016) · Nanoscale · doi:10.1039/c6nr00170j · Cited by 94
Metadata
- Authors
- Cargnello, M., Jaén, J. J. D., Garrido, J. C. H., Bakhmutsky, K., Montini, T., Gámez, J. J. C., Gorte, R. J., & Fornasiero, P.
- Venue
- Science
- Published
- 2012-08-10
- Volume
- 337
- Issue
- 6095
- Pages
- 713-717
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2037034031
- Cited by
- 1,023
- References
- 0
- FWCI
- 19.55
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Cargnello, M., Jaén, J. J. D., Garrido, J. C. H., Bakhmutsky, K., Montini, T., Gámez, J. J. C., Gorte, R. J., & Fornasiero, P. (2012). Exceptional Activity for Methane Combustion over Modular Pd@CeO 2 Subunits on Functionalized Al 2 O 3. Science. https://doi.org/10.1126/science.1222887
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