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Pulsating Tubules from Noncovalent Macrocycles
Abstract
Slip-Sliding Apart: One versatile means of synthesizing nanometer-scale cylinders has been to start with ring-shaped molecules that stack on top of each other. Huang et al. (p. 1521 ; see the Perspective by Zhang and Aida ) took this approach a step further by giving the rings a flexible diameter. Specifically, rings were prepared consisting of six v-shaped building blocks with hydrophobic sides that could slide back and forth along one another and thereby expand or contract the pore at the center. The rings spontaneously stacked to form tubes in dilute aqueous solution, and heating induced contraction of the whole tube in a process that was readily reversible on cooling.
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Citations
Cited by
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Self-citationDevelopment of Structural Complexity by Liquid‐Crystal Self‐assembly
Tschierske, C. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201300872 · Cited by 631
Supramolecular Nanostructures Formed by Anticancer Drug Assembly
Cheetham, A. G., Zhang, P., Lin, Y.-A., Lock, L. L., & Cui, H. (2013) · Journal of the American Chemical Society · doi:10.1021/ja3115983 · Cited by 517
Controlling Supramolecular Chirality in Multicomponent Self-Assembled Systems
Xing, P., & Zhao, Y. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00312 · Cited by 384
Metadata
- Authors
- Huang, Z., Kang, S.-K., Banno, M., Yamaguchi, T., Lee, D., Seok, C., Yashima, E., & Lee, M.
- Venue
- Science
- Published
- 2012-09-21
- Volume
- 337
- Issue
- 6101
- Pages
- 1521-1526
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2006532602
- Cited by
- 335
- References
- 0
- FWCI
- 13.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Huang, Z., Kang, S.-K., Banno, M., Yamaguchi, T., Lee, D., Seok, C., Yashima, E., & Lee, M. (2012). Pulsating Tubules from Noncovalent Macrocycles. Science. https://doi.org/10.1126/science.1224741
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