The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Small Gold Clusters Formed in Solution Give Reaction Turnover Numbers of 10 7 at Room Temperature
Open accessAbstract
Gold Cluster Catalysis: A variety of gold salts and complexes have been used to catalyze different organic reactions. Often, the catalytic rates for these reactions are similar. Oliver-Meseguer et al. (p. 1452 ; see the Perspective by Hashmi ) observed an induction period for the onset of catalysis of organic reactions, such as the ester-assisted hydration of alkynes, for different gold salts and complexes. Mass spectrometry and absorption spectroscopy revealed that small gold clusters (three to ten atoms) formed during these induction periods and are likely to represent the active catalysts. The catalytic reaction rates could be extremely high—up to 10 5 turnovers of the catalyst per hour.
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Cites
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Hashmi, A. S. K. (2007) · Chemical Reviews · doi:10.1021/cr000436x · Cited by 3,271
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Self-citationHighly Fluorescent, Water-Soluble, Size-Tunable Gold Quantum Dots
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Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
Liu, L., & Corma, A. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00776 · Cited by 4,777
Self-citationWell-Defined Materials for Heterogeneous Catalysis: From Nanoparticles to Isolated Single-Atom Sites
Li, Z., Ji, S., Liu, Y., Cao, X., Tian, S., Chen, Y., Niu, Z., & Li, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00311 · Cited by 1,245
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Self-citationComputational Methods in Heterogeneous Catalysis
Chen, B. W. J., Xu, L., & Mavrikakis, M. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01060 · Cited by 447
Synthetic strategies of supported atomic clusters for heterogeneous catalysis
Rong, H., Ji, S., Zhang, J., Wang, D., & Li, Y. (2020) · Nature Communications · doi:10.1038/s41467-020-19571-6 · Cited by 367
Metadata
- Authors
- Oliver-Meseguer, J., Cabrero-Antonino, J. R., Domínguez, I., Leyva-Pérez, A., & Corma, A.
- Venue
- Science
- Published
- 2012-12-14
- Volume
- 338
- Issue
- 6113
- Pages
- 1452-1455
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2086774531
- Cited by
- 411
- References
- 17
- FWCI
- 21.57
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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