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Rates of Hydrothermal Reactions
Abstract
The rates of reactions of silicates and aqueous fluids follow zero-order kinetics controlled by the reacting surface area with the rate constant given by the equation: log k ≏ -2900/ T -6.85, where T is temperature and where k has the unit's gram-atoms of oxygen per square centimeter per second. This expression appears to hold for all silicates and for reactions involving dissolution, fluid production, or solid-solid transformations in the presence of a fluid of moderate to high p H.
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Citations
Cited by
Palandri, J. L., & Kharaka, Y. K. (2004) · Open-File Report · doi:10.3133/ofr20041068 · Cited by 1,352
Putnis, A. (2009) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2009.70.3 · Cited by 1,160
Kinetics of Mineral Dissolution
Brantley, S. L. (2008) · Kinetics of Water-Rock Interaction · doi:10.1007/978-0-387-73563-4_5 · Cited by 349
The dissolution kinetics of quartz as a function of pH and time at 70°C
Knauss, K. G., & Wolery, T. J. (1988) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(88)90055-5 · Cited by 332
Fluid supersaturation and crystallization in porous media
Putnis, A., Prieto, M., & Fernandez-Diaz, L. (1995) · Geological Magazine · doi:10.1017/s0016756800011389 · Cited by 192
Metadata
- Authors
- Wood, B. J., & Walther, J. V.
- Venue
- Science
- Published
- 1983-10-28
- Volume
- 222
- Issue
- 4622
- Pages
- 413-415
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2040449064
- Cited by
- 190
- References
- 0
- FWCI
- 7.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wood, B. J., & Walther, J. V. (1983). Rates of Hydrothermal Reactions. Science. https://doi.org/10.1126/science.222.4622.413
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