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Dynamic Properties of Molecularly Thin Liquid Films
Abstract
An experimental technique is described for simultaneously measuring the static and dynamic interactions of very thin liquid films between two surfaces as they are moved normally or laterally relative to each other. Film thickness can be measured and controlled to 1 angstrom. Initial results are presented of the transition in the physical properties of liquid films only one molecular layer thick to thicker films whose properties are practically indistinguishable from the bulk. In particular, the results show that two molecularly smooth surfaces, when close together in simple liquids, slide (shear) past each other while separated by a discrete number of molecular layers, and that the frictional force is "quantized" with the number of layers.
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“Non-associating liquids, including organic solvents and oils, are known to become solid-like, with a viscosity which diverges, when confined between two surfaces as they slide past each other across films that are just a few monolayers thick [39, 40].”
From Hydration lubrication (2013) · cites this paper as [39]
In the citing paper
“For the case of organic liquids or oils, it has been realized for some time that when confined to molecularly-thin layers (in the range 5 -10 molecular diameters or less) such liquids become solid-like, and their effective viscosity diverges [39, 40, 52].”
From Hydration lubrication (2013) · cites this paper as [39]
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Research works printed but not linked: 4
- CLARKE, D.R., ANNU REV MATER SCI 17: 254 (1987).
- ISRAELACHVILI, J.N., SHEAR PROPERTIES OF MOLECULAR FILMS, NATURE-PHYSICAL SCIENCE 241: 148 (1973).
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Self-citationBhushan, B. (2011) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2011.10.019 · Cited by 53
Shear Response of Molecularly Thin Liquid Films to an Applied Air Stress
Mate, C. M., & Marchon, B. (2000) · Physical Review Letters · doi:10.1103/physrevlett.85.3902 · Cited by 53
McGuiggan, P. M., Zhang, J., & Hsu, S. M. (2001) · Tribology Letters · doi:10.1023/a:1016692704748 · Cited by 54
Self-citationSchoen, M., Diestler, D. J., & Cushman, J. H. (1994) · The Journal of Chemical Physics · doi:10.1063/1.466865 · Cited by 53
Bifurcations from steady sliding to stick slip in boundary lubrication
Batista, A. A., & Carlson, J. M. (1998) · Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics · doi:10.1103/physreve.57.4986 · Cited by 52
Boundary Lubrication and Boundary Films
Spikes, H. A. (1993) · Tribology series · doi:10.1016/s0167-8922(08)70389-4 · Cited by 52
Metadata
- Authors
- Israelachvili, J. N., McGuiggan, P. M., & Homola, A. M.
- Affiliations
- University of California, Santa Barbara (US)
- IBM Research - Almaden (US)
- Venue
- Science
- Published
- 1988-04-08
- Volume
- 240
- Issue
- 4849
- Pages
- 189-191
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2087817950
- Cited by
- 664
- References
- 22
- Citations by year
- 2025: 5 · 2024: 8 · 2023: 6 · 2022: 7 · 2021: 6 · 2020: 13 · 2019: 18 · 2018: 30 · 2017: 22 · 2016: 15 · 2015: 11 · 2014: 12 · 2013: 21 · 2012: 10
- FWCI
- 11.68
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Force Microscopy Techniques and Applications
- Physical Sciences › Engineering › Computational Mechanics › Fluid Dynamics and Thin Films
- Physical Sciences › Engineering › Mechanics of Materials › Adhesion, Friction, and Surface Interactions
- Keywords
- film thickness control, solid-liquid interface, interfacial dynamics
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