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Conducting Layered Organic-inorganic Halides Containing 〈110〉-Oriented Perovskite Sheets

Mitzi, D. B., Wang, S., Feild, C. A., Chess, C. A., Guloy, A. M.·1995·Science

Abstract

Single crystals of the layered organic-inorganic perovskites, [NH 2 C(I)=NH 2 ] 2 (CH 3 NH 3 ) m Sn m I 3 m +2 , were prepared by an aqueous solution growth technique. In contrast to the recently discovered family, (C 4 H 9 NH 3 ) 2 (CH 3 NH 3 ) n -1 Sn n I 3 n +1 , which consists of 〈100〉-terminated perovskite layers, structure determination reveals an unusual structural class with sets of m 〈110〉-oriented CH 3 NH 3 SnI 3 perovskite sheets separated by iodoformamidinium cations. Whereas the m = 2 compound is semiconducting with a band gap of 0.33 ± 0.05 electron volt, increasing m leads to more metallic character. The ability to control perovskite sheet orientation through the choice of organic cation demonstrates the flexibility provided by organic-inorganic perovskites and adds an important handle for tailoring and understanding lower dimensional transport in layered perovskites.

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Metadata

Authors
Mitzi, D. B., Wang, S., Feild, C. A., Chess, C. A., & Guloy, A. M.
Venue
Science
Published
1995-03-10
Volume
267
Issue
5203
Pages
1473-1476
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W1969815211
Cited by
808
References
0
FWCI
8.62
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Conducting Layered Organic-inorganic Halides Containing 〈110〉-Oriented Perovskite Sheets. https://app.cochat.ai/papers/10.1126/science.267.5203.1473
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Mitzi, D. B., Wang, S., Feild, C. A., Chess, C. A., & Guloy, A. M. (1995). Conducting Layered Organic-inorganic Halides Containing 〈110〉-Oriented Perovskite Sheets. Science. https://doi.org/10.1126/science.267.5203.1473

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