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A "Double-Diamond Superlattice" Built Up of Cd 17 S 4 (SCH 2 CH 2 OH) 26 Clusters
Abstract
A simple preparation of Cd 17 S 4 (SCH 2 CH 2 OH) 26 clusters in aqueous solution leads to the formation of colorless blocky crystals. X-ray structure determinations revealed a superlattice framework built up of covalently linked clusters. This superlattice is best described as two enlarged and interlaced diamond or zinc blende lattices. Because both the superlattice and the clusters display the same structural features, the crystal structure resembles the self-similarities known from fractal geometry. The optical spectrum of the cluster solution displays a sharp transition around 290 nanometers with a large absorption coefficient (∼84,000 per molar per centimeter).
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Citations
Cited by
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Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
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Qiao, R., Yang, C., & Gao, M. (2009) · Journal of Materials Chemistry · doi:10.1039/b902394a · Cited by 685
Einander durchdringende Netze: geordnete, periodische Verschlingung
Batten, S. R., & Robson, R. (1998) · Angewandte Chemie · doi:10.1002/(sici)1521-3757(19980605)110:11<1558::aid-ange1558>3.0.co;2-7 · Cited by 466
Uniform Hexagonal Plates of Vaterite CaCO3 Mesocrystals Formed by Biomimetic Mineralization
Xu, A. ‐., Antonietti, M., Cölfen, H., & Fang, Y. ‐. (2006) · Advanced Functional Materials · doi:10.1002/adfm.200500716 · Cited by 331
Metadata
- Authors
- Vossmeyer, T., Reck, G., Katsikas, L., Haupt, E. T. K., Schulz, B., & Weller, H.
- Venue
- Science
- Published
- 1995-03-10
- Volume
- 267
- Issue
- 5203
- Pages
- 1476-1479
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2037937652
- Cited by
- 360
- References
- 0
- FWCI
- 22.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: A "Double-Diamond Superlattice" Built Up of Cd 17 S 4 (SCH 2 CH 2 OH) 26 Clusters. https://app.cochat.ai/papers/10.1126/science.267.5203.1476
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- Vossmeyer, T., Reck, G., Katsikas, L., Haupt, E. T. K., Schulz, B., & Weller, H. (1995). A "Double-Diamond Superlattice" Built Up of Cd 17 S 4 (SCH 2 CH 2 OH) 26 Clusters. Science. https://doi.org/10.1126/science.267.5203.1476
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
