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Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material
Abstract
A high-capacity lithium-storage material in metal-oxide form has been synthesized that can replace the carbon-based lithium intercalation materials currently in extensive use as the negative electrode (anode) of lithium-ion rechargeable batteries. This tin-based amorphous composite oxide (TCO) contains Sn(II)-O as the active center for lithium insertion and other glass-forming elements, which make up an oxide network. The TCO anode yields a specific capacity for reversible lithium adsorption more than 50 percent higher than those of the carbon families that persists after charge-discharge cycling when coupled with a lithium cobalt oxide cathode. Lithium-7 nuclear magnetic resonance measurements evidenced the high ionic state of lithium retained in the charged state, in which TCO accepted 8 moles of lithium ions per unit mole.
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Cited by
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Metadata
- Authors
- Idota, Y., Kubota, T., Matsufuji, A., Maekawa, Y., & Miyasaka, T.
- Venue
- Science
- Published
- 1997-05-30
- Volume
- 276
- Issue
- 5317
- Pages
- 1395-1397
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2065852943
- Cited by
- 2,578
- References
- 0
- FWCI
- 42.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- Idota, Y., Kubota, T., Matsufuji, A., Maekawa, Y., & Miyasaka, T. (1997). Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material. Science. https://doi.org/10.1126/science.276.5317.1395
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
