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Magnetic Field Alignment of Ordered Silicate-Surfactant Composites and Mesoporous Silica

Tolbert, Sarah H., Firouzi, Ali, Stucky, Galen D., Chmelka, Bradley F.·1997·Science

Abstract

Macroscopic orientational ordering of the pores of condensed hexagonal mesostructured silica (MCM-41) was achieved through alignment of an unpolymerized, hexagonal, lyotropic silicate-surfactant liquid crystal in a high magnetic field. This alignment was preserved after polymerization of the silicate species by acid treatment. Subsequent calcination to remove the surfactant yielded a mesoporous silica solid that retained both macroscopic pore alignment and mesoscale periodicity. Potential applications of such liquid crystal processing strategies range from the formation of anisotropic silica-based bulk ceramics to the production of oriented mesoporous thin films for chemical sensors, separations, catalysis, or host-guest applications.

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Crossref · 10.1126/science.278.5336.264

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Metadata

Authors
Tolbert, S. H., Firouzi, A., Stucky, G. D., & Chmelka, B. F.
Venue
Science
Published
1997-10-10
Volume
278
Issue
5336
Pages
264-268
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2034190603
Cited by
320
References
0
FWCI
14.71
Type
journal article
Language
en
Open access
closed

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