Cited by 668Mesoporous Materials and CatalysisBlock Copolymer Self-AssemblyZeolite Catalysis and Synthesis

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Organically Modified Aluminosilicate Mesostructures from Block Copolymer Phases

Templin, Markus, Franck, Achim, Du Chesne, Alexander, Leist, Heike, Zhang, Yuanming, Ulrich, Ralph, Schädler, Volker, Wiesner, Ulrich·1997·Science

DOI 10.1126/science.278.5344.1795

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Abstract

Organically modified aluminosilicate mesostructures were synthesized from two metal alkoxides with the use of poly(isoprene-b-ethyleneoxide) block copolymers (PI-b-PEO) as the structure-directing molecules. By increasing the fraction of the inorganic precursors with respect to the polymer, morphologies expected from the phase diagrams of diblock copolymers were obtained. The length scale of the microstructures and the state of alignment were varied using concepts known from the study of block copolymers. These results suggest that the use of higher molecular weight block copolymer mesophases instead of conventional low-molecular weight surfactants may provide a simple, easily controlled pathway for the preparation of various silica-type mesostructures that extends the accessible length scale of these structures by about an order of magnitude.

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Authors: Templin, M., Franck, A., Du Chesne, A., Leist, H., Zhang, Y., Ulrich, R., Schädler, V., & Wiesner, U.
Affiliations: Max Planck Institute for Polymer Research (DE)
Max-Planck-Institut für Polymerforschung, Postfach 3148, 55021 Mainz, Germany.
Corresponding author: Wiesner, Ulrich
ORCID: Zhang, Yuanming
Wiesner, Ulrich
Venue: Science
Publisher: American Association for the Advancement of Science (AAAS)
Published: 1997-12-05
Volume: 278
Issue: 5344
Pages: 1795-1798
ISSN: 0036-8075 (ISSN-L)
1095-9203
DOI: 10.1126/science.278.5344.1795
OpenAlex: W2010768970
Cited by: 668
References: 36
Citations by year: 2026: 4 · 2025: 8 · 2024: 5 · 2023: 10 · 2022: 11 · 2021: 13 · 2020: 14 · 2019: 12 · 2018: 18 · 2017: 18 · 2016: 11 · 2015: 23 · 2014: 24 · 2013: 40 · 2012: 27
FWCI: 18.59
Type: journal article
Language: en
Open access: closed
Locations: Science (publishedVersion)
PubMed (publishedVersion)
Max Planck Institute for Plasma Physics (submittedVersion)
MPG.PuRe (Max Planck Society) (submittedVersion)
Topics: Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
Keywords: metal alkoxides, polymer chain alignment

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Organically Modified Aluminosilicate Mesostructures from Block Copolymer Phases

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