The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Inducing and Viewing the Rotational Motion of a Single Molecule
Abstract
Tunneling electrons from the tip of a scanning tunneling microscope were used to induce and monitor the reversible rotation of single molecules of molecular oxygen among three equivalent orientations on the platinum(111) surface. Detailed studies of the rotation rates indicate a crossover from a single-electron process to a multielectron process below a threshold tunneling voltage. Values for the energy barrier to rotation and the vibrational relaxation rate of the molecule were obtained by comparing the experimental data with a theoretical model. The ability to induce the controlled motion of single molecules enhances our understanding of basic chemical processes on surfaces and may lead to useful single-molecule devices.
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Citations
Cites
Positioning single atoms with a scanning tunnelling microscope
Eigler, D. M., & Schweizer, E. K. (1990) · Nature · doi:10.1038/344524a0 · Cited by 3,161
Cited by
Stipe, B. C., Rezaei, M. A., & Ho, W. (1999) · Review of Scientific Instruments · doi:10.1063/1.1149555 · Cited by 287
Self-citationTheoretical Investigations of the Oxygen Reduction Reaction on Pt(111)
Keith, J. A., Jerkiewicz, G., & Jacob, T. (2010) · ChemPhysChem · doi:10.1002/cphc.201000286 · Cited by 233
Water Formation on Pt and Pt‐based Alloys: A Theoretical Description of a Catalytic Reaction
Jacob, T., & Goddard, W. A. (2006) · ChemPhysChem · doi:10.1002/cphc.200500613 · Cited by 115
Metadata
- Authors
- Stipe, B. C., Rezaei, M. A., & Ho, W.
- Venue
- Science
- Published
- 1998-03-20
- Volume
- 279
- Issue
- 5358
- Pages
- 1907-1909
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2012499551
- Cited by
- 453
- References
- 1
- FWCI
- 22.37
- Type
- journal article
- Language
- en
- Open access
- closed
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- Stipe, B. C., Rezaei, M. A., & Ho, W. (1998). Inducing and Viewing the Rotational Motion of a Single Molecule. Science. https://doi.org/10.1126/science.279.5358.1907
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.