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Reversible Molecular Adsorption Based on Multiple-Point Interaction by Shrinkable Gels
Abstract
A general approach is presented for creating polymer gels that can recognize and capture a target molecule by multiple-point interaction and that can reversibly change their affinity to the target by more than one order of magnitude. The polymers consist of majority monomers that make the gel reversibly swell and shrink and minority monomers that constitute multiple-point adsorption centers for the target molecule. Multiple-point interaction is experimentally proven by power laws found between the affinity and the concentration of the adsorbing monomers within the gels.
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Citations
Cited by
Synthetische molekulare Motoren und mechanische Maschinen
Kay, E. R., Leigh, D. A., & Zerbetto, F. (2007) · Angewandte Chemie · doi:10.1002/ange.200504313 · Cited by 624
Gels with sense: supramolecular materials that respond to heat, light and sound
Jones, C. D., & Steed, J. W. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00435k · Cited by 487
Bio-inspired detoxification using 3D-printed hydrogel nanocomposites
Gou, M., Qu, X., Zhu, W., Xiang, M., Yang, J., Zhang, K., Wei, Y., & Chen, S. (2014) · Nature Communications · doi:10.1038/ncomms4774 · Cited by 323
Metadata
- Authors
- Oya, T., Enoki, T., Grosberg, A. Y., Masamune, S., Sakiyama, T., Takeoka, Y., Tanaka, K., Wang, G., Yilmaz, Y., Feld, M. S., Dasari, R., & Tanaka, T.
- Venue
- Science
- Published
- 1999-11-19
- Volume
- 286
- Issue
- 5444
- Pages
- 1543-1545
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2122086796
- Cited by
- 199
- References
- 0
- FWCI
- 4.40
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Reversible Molecular Adsorption Based on Multiple-Point Interaction by Shrinkable Gels. https://app.cochat.ai/papers/10.1126/science.286.5444.1543
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- Oya, T., Enoki, T., Grosberg, A. Y., Masamune, S., Sakiyama, T., Takeoka, Y., Tanaka, K., Wang, G., Yilmaz, Y., Feld, M. S., Dasari, R., & Tanaka, T. (1999). Reversible Molecular Adsorption Based on Multiple-Point Interaction by Shrinkable Gels. Science. https://doi.org/10.1126/science.286.5444.1543
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
