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Strong water isotopic anomalies in the martian atmosphere: Probing current and ancient reservoirs
Abstract
We measured maps of atmospheric water (H2O) and its deuterated form (HDO) across the martian globe, showing strong isotopic anomalies and a significant high deuterium/hydrogen (D/H) enrichment indicative of great water loss. The maps sample the evolution of sublimation from the north polar cap, revealing that the released water has a representative D/H value enriched by a factor of about 7 relative to Earth's ocean [Vienna standard mean ocean water (VSMOW)]. Certain basins and orographic depressions show even higher enrichment, whereas high-altitude regions show much lower values (1 to 3 VSMOW). Our atmospheric maps indicate that water ice in the polar reservoirs is enriched in deuterium to at least 8 VSMOW, which would mean that early Mars (4.5 billion years ago) had a global equivalent water layer at least 137 meters deep.
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Most estimates place the early Martian water inventory below a few hundred meters GEL.
“Although the uncertainty is considerable, most estimates place the early Martian water inventory below a few hundred meters GEL.”
From The Climate of Early Mars (2016) · cites this paper as Villanueva et al. 2015
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Sorted by citations
Wordsworth, R. D. (2016) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev-earth-060115-012355 · Cited by 416
Metadata
- Authors
- Villanueva, G. L., Mumma, M. J., Novak, R. E., Käufl, H. U., Hartogh, P., Encrenaz, T., Tokunaga, A., Khayat, A., & Smith, M. D.
- Affiliations
- Goddard Space Flight Center (US)
- Iona College (US)
- European Southern Observatory (DE)
- Max Planck Society (DE)
- Observatoire de Paris (FR)
- University of Hawaiʻi at Mānoa (US)
- Corresponding author
- Villanueva, G. L.
- Venue
- Science
- Published
- 2015-04-10
- Volume
- 348
- Issue
- 6231
- Pages
- 218-221
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1988536722
- Cited by
- 331
- References
- 1
- Citations by year
- 2026: 18 · 2025: 17 · 2024: 28 · 2023: 23 · 2022: 23 · 2021: 30 · 2020: 33 · 2019: 56 · 2018: 30 · 2017: 28 · 2016: 28 · 2015: 15
- FWCI
- 19.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- MPG.PuRe (Max Planck Society) (submittedVersion)
- Funders
- NSF Research in Undergraduate Institutions (AST 0805540)
- NASA Keck PI Data Award
- Topics
- Physical Sciences › Earth and Planetary Sciences › Space and Planetary Science › Planetary Science and Exploration
- Physical Sciences › Earth and Planetary Sciences › Space and Planetary Science › Astro and Planetary Science
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Keywords
- Mars atmosphere, stable water isotopes, deuterium/hydrogen ratio, HDO, water loss, early Mars
- MeSH terms
- Atmosphere, Deuterium, Extraterrestrial Environment, Ice, Water, Deuterium Oxide, Mars, Evolution, Planetary
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