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Activation of Cu(111) surface by decomposition into nanoclusters driven by CO adsorption
Open accessAbstract
Nanoclusters just by adding CO: The most closely packed surfaces of transition metals are usually stable under vacuum, but during catalytic reactions, energetic changes that result from adsorbing molecules could change the surface structure. Eren et al. present an extreme example for carbon monoxide (CO) adsorption on the (111) surface of copper at very low partial pressures. The surface decomposed into small nanoclusters (most containing 3 or 19 atoms). The surface was more reactive than the original and, for example, could dissociate adsorbed water at room temperature. Science , this issue p. 475
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From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Surface engineering for stable electrocatalysis
Do, V.-H., & Lee, J.-M. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00292f · Cited by 167
Metadata
- Authors
- Eren, B., Zherebetskyy, D., Patera, L. L., Wu, C. H., Bluhm, H., Africh, C., Wang, L.-W., Somorjai, G. A., & Salmeron, M.
- Venue
- Science
- Published
- 2016-01-29
- Volume
- 351
- Issue
- 6272
- Pages
- 475-478
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2333714774
- Cited by
- 377
- References
- 1
- FWCI
- 13.82
- Type
- journal article
- Language
- en
- Open access
- green
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- Eren, B., Zherebetskyy, D., Patera, L. L., Wu, C. H., Bluhm, H., Africh, C., Wang, L.-W., Somorjai, G. A., & Salmeron, M. (2016). Activation of Cu(111) surface by decomposition into nanoclusters driven by CO adsorption. Science. https://doi.org/10.1126/science.aad8868
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